Solid anti-friction devices – materials therefor – lubricant or se – Lubricants or separants for moving solid surfaces and... – Organic -co- compound
Reexamination Certificate
2001-03-22
2003-12-23
Howard, Jacqueline V. (Department: 1764)
Solid anti-friction devices, materials therefor, lubricant or se
Lubricants or separants for moving solid surfaces and...
Organic -co- compound
C508S433000, C508S459000, C508S591000, C508S551000, C508S579000, C508S583000, C558S208000, C558S209000, C562S503000, C564S080000, C564S189000, C568S838000
Reexamination Certificate
active
06667284
ABSTRACT:
FEDERALLY SPONSORED RESEARCH STATEMENT
Not applicable.
REFERENCE TO MICROFICHE APPENDIX
Not applicable.
FIELD OF THE INVENTION
The invention relates to a method of manufacturing a magnetic recording medium having a lubricant film formed thereon. Furthermore, the invention also relates to a data recording/retrieval device which incorporates such magnetic recording media.
BACKGROUND OF THE INVENTION
Thin-film magnetic recording disks and disk drives are commonly used for storing a large amount of data in magnetizable form. Over the last decade, magnetic recording has become the predominant technology for the storage of digital information in modern computer systems.
Magnetic recording generally is accomplished by the relative motion between a magnetic medium and a magnetic recording head. A magnetic recording head consists of a small electromagnet with a gap facing the magnetic medium. During writing, a current is applied to the windings of the electromagnet, thus creating a fringing field at the head gap and magnetizing the magnetic medium according to the direction of the current applied to the head. During reading, the flux from the magnetic medium is intercepted from the head core, inducing a voltage pulse in the coil of the read head.
FIGS. 1A and 1B
illustrate a typical disk drive.
FIG. 1A
is a top plan view of the disk drive, and
FIG. 1B
is a side view of the disk drive. The disk drive
10
generally includes a magnetic disk
11
and a disk head
16
for writing and reading information to and from the magnetic disk
11
. The disk head
16
may include a read/write element
12
and a slider
13
. The disk head
16
is connected to a suspension arm
14
, which is, in turn, connected to a rotary actuator
15
.
A common method to store or retrieve data is called contact start/stop (also known as “CSS”). In a typical CSS operation, the disk head and the surface of the magnetic disk are set so that they are in contact with each other at the start of the operation. Thereafter, a space of an air layer is formed between the head and the surface of the magnetic disk by giving a predetermined rotation to the magnetic disk. In this state, recording or reproduction of data is performed. At the end of the operation, the rotation of the magnetic disk is stopped. At this point, the head and the surface of the magnetic disk are in a frictional contact state as when the operation is started. The frictional force produced between the head and the magnetic disk in this frictional contact state wears the head and the magnetic disk. Eventually, this frictional force may damage the head and the magnetic disk. Furthermore, in the frictional contact state, a slight change in altitude of the head sometimes renders the load on the head non-uniform, thus resulting in damage to the head and the surface of the magnetic disk.
To prevent the wear of the magnetic disk caused by the contact with and sliding on the head, a lubricant layer is provided on the surface of the magnetic disk. A common lubricant used in magnetic disks is perfluoropolyether (“PFPE”). To increase the wear resistance of the magnetic disk and to protect the magnetic material from the corrosive effect of the PFPE lubricant, a protective layer is sometimes provided between the magnetic medium and the lubricant layer. The protective layer may include amorphous carbon, diamond-like carbon, and other materials.
Due to the prevalent use of computers, increases in the areal data storage density of a magnetic disk have continued rapidly and unabatedly for almost 40 years. The trend towards high recording densities is expected to continue. For example, the current areal density is about 0.5 gigabytes per square inch. The next generation disks are going to have an areal density of about 10 gigabytes per square inch. In a few years, the areal density is expected to exceed 40 gigabytes per square inch. To achieve a high recording density, the magnetic head should be positioned as close as possible to the surface of the magnetic medium. The distance between the tip of the magnetic head and the surface of the magnetic medium is referred to as “flight height.” For example, to achieve an areal density of about 0.5 gigabytes per square inch, a flight height in the range of about 25-30 nm is required. To achieve an areal density of 10 gigabytes per square inch, the flight height should be decreased to about 10-15 nm. If an areal density of 40 gigabytes per square inch is desired, the flight height should be further decreased to about 3.5 nm. This means that the thickness of the lubricant layer (or film) and the thickness of the protective layer should sum to about 3 nm or less. Consequently, the reliability of the head-disk interface becomes more dependent on the life and performance of the lubricant film as the conquest for higher density disks continues. In other words, the characteristics of the lubricant film, such as its physical, chemical, and tribological properties, have a critical impact on the performance of such high density disks.
First, the lubricant film or layer should last for the lifetime of the drive. If the lubricant layer wears away prematurely, the disk drive would fail accordingly. Furthermore, the lubricant layer should be resistant to chemical degradation. Chemical degradation of the lubricant layer can be induced by thermal decomposition, catalytic reaction with solid surfaces, and mechanical shearing due to high-speed contact with the disk head.
In addition to chemical stability, a major challenge in developing disk lubricant systems is to provide adequate durability without increasing stiction to unacceptable levels. During the lifetime of a magnetic disk, the disk head goes through thousands stop-and-start cycles. If the static friction forces between the disk head and the magnetic medium becomes too large, the drive motor may not develop sufficient torque to restart disk spinning. This may lead to failure of the disk drive.
As mentioned above, PFPEs have been used extensively to form a lubricant film in a magnetic recording medium. PFPEs are relatively expensive. Therefore, cheaper alternatives are more desirable. Although PFPEs have good thermal stability, they decompose readily when they are in contact with Lewis acids. This is an important consideration because the head often is fabricated from an Al
2
O
3
/TiC composite, and Al
2
O
3
can be converted to AlF
3
, a strong Lewis acid. This formation of AlF
3
leads to chemical degradation of PFPE lubricants. Moreover, use of chlorofluorohydrocarbons (“CFCs”) as solvent generally is involved when PFPEs are applied to a magnetic medium. CFCs have detrimental effects on the ozone layer, and use thereof should be avoided, if possible.
In view of the foregoing discussion, in order to meet the challenge of the information age, there is a need to develop magnetic recording media with a lubricant layer that is more chemically and mechanically robust to withstand high shear rates and harsh environments. The lubricant layer should allow decreased flight height so that higher areal densities may be achieved. Furthermore, it is desirable that such lubricant be relatively inexpensive, and that no CFCs be used in forming the lubricant layer.
SUMMARY OF THE INVENTION
The above need is met by a class of hydrocarbyl-substituted cyclopentenes, hydrocarbyl-substituted cyclopentanes, hydrocarbyl-substituted cyclopentadienes, and mixtures or derivatives thereof which may be used to form a lubricant layer over a magnetic layer in a magnetic recording medium.
In one aspect, the invention relates to a magnetic recording medium. The magnetic recording medium includes: (1) a non-magnetic substrate; (2) a magnetic layer formed on the substrate; (3) a lubricant layer over the magnetic layer, where the lubricant layer includes a compound selected from the group consisting of hydrocarbyl-substituted cyclopentanes, hydrocarbyl-substituted cyclopentenes, hydrocarbyl-substituted cyclopentadienes, and mixtures or derivatives thereof. In some embodiments, the magnetic recording medium may further in
Chiu I-Ching
Gunsel Selda
Venier Clifford
Howard Jacqueline V.
Jenkens & Gilchrist
Pennzoil-Quaker State Company
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