Low temperature vulcanizing carborane siloxane adhesive

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From boron reactant having at least one boron to hydrogen or...

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528 15, C08G 7722

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active

052908976

ABSTRACT:
A carborane siloxane base polymer is formulated into a crosslinked, rubbery high temperature material by incorporating a vinyl group in the backbone of the polymer. By careful control of process variables, the crosslinked polymer allows formation of optically clear and thermally stable adhesive bonds between a number of substrates. While curing is conveniently done at ambient temperature, the adhesive can withstand thermal cycling to over 600.degree. C.

REFERENCES:
patent: 4145504 (1979-03-01), Hedaya et al.
patent: 4208492 (1980-06-01), Hedaya et al.
patent: 5208310 (1993-05-01), Dougherty
Eaborn, Organosilicon Compounds, pp. 2, 3 and 4, Academic Press, N.Y., 1960.
D. D. Stewart et al, "D.sub.2 -m-Carborane Siloxanes. 7. Synthesis and properties of Ultra-High Molecular Weight Polymer", Macromolecules, vol. 12, No. 3, pp. 373-377 (1979).
E. Hedaya et al, "D.sub.2 -meta-Carborane-Siloxanes. IV. Synthesis of Linear, High Molecular Weight Polymers", Journal of Polymer Science, Polymer Chemistry Edition, vol. 15, pp. 2229-2238 (1977).

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