Low-temperature solidification of radioactive and hazardous...

Hazardous or toxic waste destruction or containment – Destruction or containment of radioactive waste – By fixation in stable solid media

Reexamination Certificate

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C588S012000

Reexamination Certificate

active

07855313

ABSTRACT:
Treatment of a radioactive waste stream is provided by adding sodium hydroxide (NaOH) and/or potassium hydroxide (KOH) together with a rapidly dissolving form of silica, e.g., fumed silica or fly ash. Alternatively, the fumed silica can be first dissolved in a NaOH/KOH solution, which is then combined with the waste solution. Adding a binder that can be a mixture of metakaolin (Al2O3.2SiO2), ground blast furnace slag, fly ash, or other additives. Adding an “enhancer” that can be composed of a group of additives that are used to further enhance the immobilization of heavy metals and key radionuclides such as99Tc and129I. An additional step can involve simple mixing of the binder with the activator and enhancer, which can occur in the final waste form container, or in a mixing vessel prior to pumping into the final waste form container, depending on the particular application.

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Hyatt, Neil “Zeolite-Salt Occlusion: A Potential Route for the Immobilisation fo Iodine-129?” The University of Birmingham. (2004).
Sharp, J.H. et al., “Cementitious Systems for Encapsulation of Intermediate Level Waste”, Proceedings of ICEM 03' The 9th International Conference on Radioactive Waste Management and Environmental Remediation. Examination School. Oxford, England, (Sep. 21-25, 2003).
Zhou, Q., et al. “An Alternative to Portland Cement for Waste Encapsulation—the calcium sulfoaluminate cement system” Journal of Hazardous Materials 136 (2006) 120-129.

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