Low temperature reforming process for production of hydrogen...

Gas: heating and illuminating – Processes – Manufacture from methane

Reexamination Certificate

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C048S127100, C048S21400A, C048S1990FM, C423S648100

Reexamination Certificate

active

07459000

ABSTRACT:
A hydrogen production process with high hydrogen yield at a low temperature is described. First, an aqueous methanol solution with water/methanol molar ratio between about 0.75 and about 2.5 is pre-mixed with oxygen in an oxygen/methanol molar ratio not greater than about 0.5. The mixture is then directed to pass through an activated supported gold catalyst undergoing an oxidative steam reforming of methanol to generate a hydrogen-rich gas with CO content less than 1% at a low reaction temperature (TR>150° C.). Gold particles on active supported gold catalysts have been dispersed to a size of 6 nm or less. The oxidative steam reforming of methanol may generate more than 2 moles of hydrogen for each mole of methanol consumed.

REFERENCES:
patent: 5759949 (1998-06-01), Grigorova et al.
patent: 6165633 (2000-12-01), Negishi
patent: 2002/0012828 (2002-01-01), Grigorova et al.
patent: 2006/0128565 (2006-06-01), Flytzani-Stephanopoulos et al.
patent: WO 97/45192 (1997-12-01), None
patent: WO 99/16546 (1999-04-01), None

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