Low shrinkable unsaturated polyester resin composition

Details Low shrinkable unsaturated polyester resin composition Low shrinkable unsaturated polyester resin composition

1984-12-26

1986-06-03

Bleutge, John C.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Mixing of two or more solid polymers; mixing of solid...

525170, 525299, C08L 6706

Patent

active

045930678

ABSTRACT:
Disclosed herein is a low shrinkable unsaturated polyester resin composition consisting of (A) 20-70% by weight of an unsaturated polyester, (B) 28-60% by weight of a monomer polymerizable with the above unsaturated polyester, and (C) 2-20% by weight of a block copolymer mixture. The mixtures of the monomer (B) and the block copolymer mixture (C), and a mixture of the polyester (A), the monomer (B), and the block copolymer mixture (C) are in a non-aqueous dispersion state. The block copolymer mixture is obtained by polymerizing either one of the monomers defined below in (a) and (b) with a polymerization initiator a polymeric perioxide represented by the formula: ##STR1## in which R.sub.1 represents a divalent branched hydrocarbon group having 10-30 carbons, and R.sub.2 and R.sub.3 represent a hydrogen atom, a hydroxyl group or an alkali metal, and the average polymerization degree n is 2-40, and is used to obtain a first polymer having peroxy bonds in its molecule, and block-polymerizing the first polymer with the remaining monomer (a) or (b) which has not been used in the first polymerization reaction wherein, (a) is a monomer or a monomer mixture consisting of 70-100% by weight of styrene monomer and 30-0% by weight of a monomer polymerizable therewith.

REFERENCES:
patent: 3992479 (1976-11-01), Roberts
patent: 4303762 (1981-12-01), Nakayama
patent: 4374215 (1983-02-01), Atkins

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