Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...
Reexamination Certificate
2000-02-25
2003-06-17
Cain, Edward J. (Department: 1714)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
At least one aryl ring which is part of a fused or bridged...
C524S439000, C524S440000
Reexamination Certificate
active
06579931
ABSTRACT:
TECHNICAL FIELD
The present invention relates to conductive polymer compositions which exhibit PTC behavior, and particularly PTC compositions which utilize a coupling agent.
BACKGROUND OF THE INVENTION
It is well known that the resistivity of many conductive materials change with temperature. The resistivity of a positive temperature coefficient (PTC) conductive material sharply increases as the temperature of the material increases over a particular range. Many crystalline polymers, made electrically conductive by dispersing conductive fillers therein, exhibit this PTC effect. These polymers generally include polyolefins such as polyethylene, polypropylene and ethylene/propylene copolymers. At temperatures below a certain value, i.e., the critical or trip temperature, the polymer exhibits a relatively low, constant resistivity. However, as the temperature of the polymer increases beyond the critical point, the resistivity of the polymer sharply increases. Compositions exhibiting PTC behavior have been used in electrical devices as over-current protection in electrical circuits comprising a power source and additional electrical components in series. Under normal operating conditions in the electrical circuit, the resistance of the load and the PTC device is such that relatively little current flows through the PTC device. Thus, the temperature of the device (due to I
2
R heating) remains below the critical or trip temperature. If the load is short circuited or the circuit experiences a power surge, the current flowing through the PTC device increases greatly. At this point, a great deal of power is dissipated in the PTC device. This power dissipation only occurs for a short period of time (fraction of a second), however, because the power dissipation will raise the temperature of the PTC device (due to I
2
R heating) to a value where the resistance of the PTC device has become so high, that the current is limited to a negligible value. The new current value is enough to maintain the PTC device at a new, high temperature/high resistance equilibrium point. The device is said to be in its “tripped” state. The negligible or trickle through current that flows through the circuit will not damage the electrical components which are connected in series with the PTC device. Thus, the PTC device acts as a form of a current limiter, reducing the current flow through the short circuit load to a safe, low value when the PTC device is heated to its critical temperature range. Upon interrupting the current in the circuit, or removing the condition responsible for the short circuit (or power surge), the PTC device will cool down below its critical temperature to its normal operating, low resistance state. The effect is a resettable, electrical circuit protection device.
Conductive polymer PTC compositions and their use as protection devices are well known in the industry. For example, U.S. Pat. No. 4,237,441 (Van Konynenburg et al.), U.S. Pat. No. 4,304,987 (Van Konynenburg), U.S. Pat. No. 4,545,926 (Fouts, Jr. et al.), U.S. Pat. No. 4,849,133 (Yoshida et al.), U.S. Pat. No. 4,910,389 (Sherman et al.), U.S. Pat. No. 5,106,538 (Barma et al.), and U.S. Pat. No. 5,880,668 (Hall) and EP-730 282 A2 (Unitika) disclose PTC compositions which comprise a thermoplastic crystalline polymer with carbon black dispersed therein. The disclosure of each one of these references is herein incorporated by reference. Conventional polymer PTC electrical devices include a PTC element interposed between a pair of electrodes. The electrodes can be connected to a source of power, thus, causing electrical current to flow through the PTC element.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide a conductive polymer PTC composition with a low room temperature resistivity. Accordingly, in a first aspect of the present invention there is provided a crystalline conductive polymer composition exhibiting PTC behavior, the composition comprising a polyolefin, a conductive particulate filler and a coupling agent.
In a second aspect of the invention, the composition is comprised of a polyolefin in a range of about 45% to 65% by weight of the total composition, a conductive filler in a range of about 35% to 50% by weight of the total composition, and a coupling agent in a range of about 0.1% to 1.0% by weight of the total composition.
In a preferred embodiment of the present invention, the coupling agent comprises an organo-metallic compound. It is believed that the coupling agent promotes the uniform dispersion of the conductive filler throughout the polyolefin. As a result, PTC compositions which include a coupling agent according to the present invention have much lower room temperature resistivities than PTC compositions which do not include a coupling agent. In some cases, the reduction in resistivity is as great as 75%.
Other advantages and aspects of the present invention will become apparent upon reading the following detailed description of the invention.
DETAILED DESCRIPTION
While this invention is susceptible of embodiment in many different forms, there is shown in the examples and will herein be described in detail embodiments and methods of manufacture with the understanding that the present disclosure is to be considered as an exemplification of the principles of the invention and is not intended to limit the broad aspect of the invention to the embodiments illustrated.
The polymer component used in compositions of the present invention may be a single polymer or a mixture of two or more polymers. Generally, the polymer component may comprise a polyolefin having a crystallinity of at least 30%, and preferably more than 70%. Suitable polyolefins include polyethylene, polypropylene, polyvinyladene fluoride, copolymers of polyethylene, polypropylene, ethylene/propylene copolymers, polybutadiene, polyethylene acrylates, and ethylene acrylic acid copolymers.
The polymer component used in the present invention may also be a modified polyolefin. The term modified polyolefin as used herein is defined as a polyolefin having a carboxylic acid or a carboxylic acid derivative. grafted thereto. The carboxylic acid or the carboxylic acid derivative can comprise as much as 10% by weight of the modified polyolefin, preferably 5% by weight of the modified polyolefin, more preferably 3% by weight of the modified polyolefin, especially 1% by weight oft modified polyolefin. An example of PTC compositions and electrical devices utilizing modified polyolefins is disclosed in U.S. Pat. No. 5,880,668, the disclosure of which is incorporated herein by reference.
Suitable conductive particulate fillers for use in the present invention include nickel powder, silver powder, gold powder, copper powder, silver-plated copper powder, powders of metal alloys, carbon black, carbon powder, and graphite. Preferably, the conductive particulate filler comprises about 35% to about 50% by weight of the total composition.
The coupling agents used in the present invention are preferably comprised of an organo-metallic compound. Suitable examples of such compounds fall under the classifications of neoalkoxy titanates and neoalkoxy zirconates manufactured by Kenrich Petrochemical, Inc. located in Bayonne, N.J.
Specific examples of neoalkoxy titanates include: titanium IV 2,2(bis 2-propenolatomethyl) butanolato, tris neodecanoato-0, titanium IV 2,2(bis 2-propenolatomethyl) butanolato, tris(dodecyl) benzenesulfonato-0, titanium IV 2,2 (bis 2-propenolatomethyl) butanolato, tris(dioctyl) phosphato-0, titanium IV 2,2 (bis 2-propenolatomethyl) butanolato, tris(dioctyl) pyrophosphato-0, titanium IV 2,2(bis 2-propenolatomethyl) butanolato, tris(2-ethylenediamino) ethylato, titanium IV 2,2 (bis 2-propenolatomethyl) butanolato, tris(3-amino) phenylato, and titanium IV 2,2 (bis 2-propenolatomethyl) butanolato, tris(6-hydroxy) hexanoato-0.
Specific examples of neoalkoxy zirconates include: zirconium IV 2,2 (bis-2-propenolatomethyl) butanolato, tris neodecanolato-0, zirconium IV 2,2 (bis-2-propenolatomethyl) butanolato, tris(dodecyl) benzen
Bell Boyd & Lloyd LLC
Littelfuse Inc.
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