Low NO x FCC catalyst regeneration process

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Cracking

Reexamination Certificate

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Reexamination Certificate

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07914666

ABSTRACT:
An FCC process producing lower NOx emissions during regeneration by using excess oxygen levels at less than or equal to about 0.5 mol-% and a plenum temperature above about 730° C. (about 1350° F.). The process may further include limiting the Pt content in the catalyst to less than or equal to about 0.5 ppm. NOxemissions, NO to NO2, produced through this process may be equal to or less than 25 ppmv. The process may also include adjusting the metal content of the feedstock for such metals as antimony, nickel, or vanadium. Additional variables for reducing NOxemissions that may be used in conjunction with this process may include increasing the flue gas residence time, injecting NH3into the flue gas, adding or using NOx-reducing catalysts, increasing stripping of the catalyst, and increasing the catalyst zeolite to matrix ratio.

REFERENCES:
patent: 3245920 (1966-04-01), Keith et al.
patent: 4778665 (1988-10-01), Krishnamurthy et al.
patent: 4784752 (1988-11-01), Ramamoorthy et al.
patent: 4812430 (1989-03-01), Child
patent: 4851374 (1989-07-01), Yan et al.
patent: 4986897 (1991-01-01), Chin

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