Low K-factor closed cell phenol-aldehyde foam and process for pr

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Cellular products or processes of preparing a cellular...

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Details

521112, 521117, 521121, 521181, C08J 914

Patent

active

045309396

ABSTRACT:
Generally closed cell phenolic foams are prepared which have a K-factor of less than 0.2, preferably from about 0.116 to about 0.170 Btu/hr - .degree.F. - ft - .sup.2 per inch of foam thickness when measured at 24.degree. Centigrade. The foams are prepared from a resole resin which has been stripped to a water level of less than 7 percent by weight, preferably from about 3 to about 6 percent by weight based on resin weight. A viscosity adjusting amount of a solvent, such as phenol, and from about 10 to about 20 weight percent, based on resin weight, of a polyglycol are also part of a foam forming formulation. Conventional surfactants, blowing agents and acidic catalysts are used to prepare the foams. The foams so prepared generally have no tendency to autoxidize when placed in an oven heated to a temperature of 250.degree. Centigrade. The foams so prepared also have enhanced resistance to flame penetration.

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