Compositions – Gaseous compositions – Carbon-oxide and hydrogen containing
Patent
1997-10-31
1999-11-16
Killos, Paul J.
Compositions
Gaseous compositions
Carbon-oxide and hydrogen containing
C07C 102
Patent
active
059851783
ABSTRACT:
A process for making a synthesis gas comprising H.sub.2 and CO in the presence of a reforming catalyst comprising a supported non-noble Group VIII metal catalytic component from a feed including a low molecular weight alkane, and preferably methane as in natural gas, O.sub.2, H.sub.2 O and CO.sub.2 without catalyst deactivation is achieved by partially oxidizing and steam reforming the feed in the presence of the catalyst. The feed H.sub.2 O to hydrocarbon carbon mole ratio is less than 2. The mole ratio of the combined feed CO.sub.2 and H.sub.2 O to hydrocarbon carbon ranges from 0.5-2.5 and that of the feed H.sub.2 O to CO.sub.2 ranges from 0.35-6. Synthesis gas having H.sub.2 to CO mole ratios less than 2:1 and even less than 1.5:1 are easily achieved with net CO.sub.2 consumption, which also makes the process environmentally beneficial.
REFERENCES:
patent: 4877550 (1989-10-01), Goetsch et al.
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patent: 5143647 (1992-09-01), Say et al.
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patent: 5421840 (1995-06-01), Taylor et al.
Fiato Rocco A.
Long David C.
Exxon Research and Engineering Co.
Killos Paul J.
Parsa J.
Simon Jay
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