Low hydrogen embrittlement zinc/nickel plating for high...

Electrolysis: processes – compositions used therein – and methods – Electrolytic coating – Depositing predominantly alloy coating

Reexamination Certificate

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C205S208000, C205S217000, C205S224000

Reexamination Certificate

active

08048285

ABSTRACT:
The invention provides a method for producing a corrosion-resistant article, where the article is conductive and subject to hydrogen uptake during electroplating of a coating. The method comprises electroplating a zinc
ickel coating on the article in an aqueous, basic plating solution containing zinc and nickel ions. The method uses an electrolyte in the form of a soluble hydroxide salt with the weight ratio of zinc ions to nickel ions in the solution being sufficient to provide the coating comprising from about 85% to about 95% by weight zinc, and about 5% to about 15% by weight nickel. The plating solution is substantially free of brightening agents which retard hydrogen bake-out.

REFERENCES:
patent: 3691027 (1972-09-01), Hartford et al.
patent: 3972789 (1976-08-01), Eppensteiner et al.
patent: 4765871 (1988-08-01), Hsu et al.
patent: 4877496 (1989-10-01), Yanagawa et al.
patent: 4889602 (1989-12-01), Oshima et al.
patent: 5417840 (1995-05-01), Block et al.
patent: 2005/0133376 (2005-06-01), Opaskar et al.
Atotech Product Literature, Reflectalloy ZNA, revised Dec. 9, 2004, 5 pages.
Atotech Product Literature, Reflectalloy® ZNA, Alkaline Zinc-Nickel Plating Process, revised Apr. 29, 2003, pp. 1-17.

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