Low-fire ceramic dielectric compositions for multilayer ceramic

Electricity: electrical systems and devices – Electrostatic capacitors – Fixed capacitor

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H01G 412

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044995210

ABSTRACT:
A low fire ceramic dielectric composition, a multilayer capacitor made from such a ceramic dielectric composition provided with silver/palladium electrodes having at least 65 atomic percent silver, and a method of manufacturing such a multilayer capacitor. The ceramic is barium titanate-based and includes Bi.sub.2 O.sub.3, Nb.sub.2 O.sub.5, and TiO.sub.2 to improve sinterability. MnCO.sub.3 is added to increase the insulation resistance. The multilayer capacitor includes high silver-content electrodes to reduce the quantity of expensive noble metals. The multilayer part may be fired at a temperature of 1150.degree. C. or less to yield a capacitor meeting EIA specification X7R. The low firing temperature also inhibits a chemical reaction between bismuth and palladium.

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patent: 4379854 (1983-04-01), Soong
Maher, G. H. "Improved Dielectrics for Multi-Layer Ceramic Capacitors", 27th Electronic Components Conference, Arlington, Va. (May 16-18, 1977), pp. 391-399.
Crownover, J. W. "A Low Firing K3000 (X7R) Dielectric", Proceed. of 28th Electronic Components Conf., Anaheim, Ca., (Apr. 24-26, 1978), pp. 204-206.
M. Hansen, Constitution of Binary Alloys, pp. 41 and 42, McGraw-Hill (1958).
R. B. Amin et al., Abstract Precious Metal Electrode Systems for Multilayer Ceramic Capacitors, Nat'l Materials Adv. Bd. Workshops on Reliability of Multilayer Capacitors, (Mar. 1982).

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