Low expansion transparent crystallized glass-ceramic

Compositions: ceramic – Ceramic compositions – Devitrified glass-ceramics

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501 7, 501 69, C03C 1014

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active

053366433

ABSTRACT:
A low expansion crystallized glass-ceramic which has a coefficient of thermal expansion (.alpha..times.10.sup.-7 /.degree. C.) within the range of from -10 to +10, has a remarkably reduced variation in the coefficient of thermal expansion accompanied by variation in heat treatment conditions, has an excellent optical homogeniety owing to reduced melting temperature in the base glass and has an improved transparency is obtained by restricting the ratio in weight of Al.sub.2 O.sub.3 to (SiO.sub.2 +P.sub.2 O.sub.5) within the range of 0.38 and 0.50 and adding MgO, BaO and ZnO of specific content ranges as essential ingredients in a base glass of a SiO.sub.2 -Al.sub.2 O.sub.3 -Li.sub.2 O system containing P.sub.2 O.sub.5 as an optional ingredient and TiO.sub.2 and ZrO.sub.2 as nucleating agents.

REFERENCES:
patent: 4093468 (1978-06-01), Boitel et al.
patent: 5070045 (1991-12-01), Comte et al.
patent: 5179045 (1993-01-01), Aitken et al.

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