Low defect density silicon having a vacancy-dominated core...

Single-crystal – oriented-crystal – and epitaxy growth processes; – Processes of growth from liquid or supercritical state – Having pulling during growth

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C117S019000, C117S020000

Reexamination Certificate

active

11005987

ABSTRACT:
The present invention relates to a process for preparing a single crystal silicon ingot, as well as to the ingot or wafer resulting therefrom. The process comprises controlling (i) a growth velocity, v, (ii) an average axial temperature gradient, G0, and (iii) a cooling rate of the crystal from solidification to about 750° C., in order to cause the formation of a segment having a first axially symmetric region extending radially inward from the lateral surface of the ingot wherein silicon self-interstitials are the predominant intrinsic point defect, and a second axially symmetric region extending radially inward from the first and toward the central axis of the ingot. The process is characterized in that v, G0and the cooling rate are controlled to prevent the formation of agglomerated intrinsic point defects in the first region, while the cooling rate is further controlled to limit the formation of oxidation induced stacking faults in a wafer derived from this segment, upon subjecting the wafer to an oxidation treatment otherwise suitable for the formation of such faults.

REFERENCES:
patent: 3997368 (1976-12-01), Petroff et al.
patent: 4314595 (1982-02-01), Yamamoto et al.
patent: 4350560 (1982-09-01), Helgeland et al.
patent: 4981549 (1991-01-01), Yamashita et al.
patent: 5264189 (1993-11-01), Yamashita et al.
patent: 5316742 (1994-05-01), Tomioka et al.
patent: 5441014 (1995-08-01), Tomioka et al.
patent: 5474020 (1995-12-01), Bell et al.
patent: 5485803 (1996-01-01), Habu
patent: 5487354 (1996-01-01), von Ammon et al.
patent: 5494849 (1996-02-01), Iyer et al.
patent: 5502010 (1996-03-01), Nadahara et al.
patent: 5567399 (1996-10-01), von Ammon et al.
patent: 5593494 (1997-01-01), Falster
patent: 5667584 (1997-09-01), Takano et al.
patent: 5704973 (1998-01-01), Sakurada et al.
patent: 5728211 (1998-03-01), Takano et al.
patent: 5789309 (1998-08-01), Hellwig
patent: 5846322 (1998-12-01), Schulmann et al.
patent: 5919302 (1999-07-01), Falster et al.
patent: 5935320 (1999-08-01), Graef et al.
patent: 5942032 (1999-08-01), Kim et al.
patent: 5954873 (1999-09-01), Hourai et al.
patent: 5958133 (1999-09-01), Boulaev et al.
patent: 5968262 (1999-10-01), Saishouji et al.
patent: 5968264 (1999-10-01), Iida et al.
patent: 5994761 (1999-11-01), Falster et al.
patent: 6045610 (2000-04-01), Park et al.
patent: 6048395 (2000-04-01), Iida et al.
patent: 6053974 (2000-04-01), Luter et al.
patent: 6066366 (2000-05-01), Berenbaum et al.
patent: 6093913 (2000-07-01), Schrenker et al.
patent: 6120599 (2000-09-01), Iida et al.
patent: 6153008 (2000-11-01), von Ammon et al.
patent: 6197111 (2001-03-01), Ferry et al.
patent: 6228164 (2001-05-01), von Ammon et al.
patent: 6236104 (2001-05-01), Falster
patent: 6245430 (2001-06-01), Hourai et al.
patent: 6254672 (2001-07-01), Falster et al.
patent: 6312516 (2001-11-01), Falster et al.
patent: 6336968 (2002-01-01), Falster et al.
patent: 0 503 816 (1992-09-01), None
patent: 0 504 837 (1992-09-01), None
patent: 0 536 958 (1993-04-01), None
patent: 0 909 840 (1999-04-01), None
patent: 0 962 556 (1999-12-01), None
patent: 0 962 557 (1999-12-01), None
patent: 0 990 718 (2000-05-01), None
patent: 2 137 524 (1984-10-01), None
patent: 2 182 262 (1987-05-01), None
patent: 1145391 (1989-06-01), None
patent: 2-180789 (1990-07-01), None
patent: 2-267195 (1990-10-01), None
patent: HEI 3-93700 (1991-04-01), None
patent: 4-042893 (1992-02-01), None
patent: 4-108682 (1992-04-01), None
patent: 2528309 (1996-08-01), None
patent: HO 8-268794 (1996-10-01), None
patent: 8-330316 (1996-12-01), None
patent: HO 9-202690 (1997-08-01), None
patent: 11043396 (1999-02-01), None
patent: 11-157995 (1999-06-01), None
patent: 11-180800 (1999-07-01), None
patent: 11-189495 (1999-07-01), None
patent: 11-199386 (1999-07-01), None
patent: 11-199387 (1999-07-01), None
patent: WO 97/26393 (1997-07-01), None
patent: WO 98/45507 (1998-10-01), None
patent: WO 98/45508 (1998-10-01), None
patent: WO 98/45510 (1998-10-01), None
patent: WO 00/14776 (2000-03-01), None
patent: WO 00/22196 (2000-04-01), None
patent: WO 00/22198 (2000-04-01), None
patent: WO 01/21861 (2001-03-01), None
patent: WO 01/21865 (2001-03-01), None
Abe, T., et al., “Swirl Defects in Float-Zoned Silicon Crystals,” Physics., vol. 116B, (1985), pp. 139-147.
Abe, T., et al., “The Characteristics of Nitrogen in Silicon Crystals,” VLSI Science and Technology/1985, (Electrochem. Soc. Pennington, 1985), Proceedings vol. 85-5, (1985), pp. 543-551.
Abe, T., et al., “Behavior of Point Defects in FZ Silicon Crystals,” Semiconductor Silicon 1990,Proceedings of the Sixth International Symposium on Silicon Materials Science and Technology, vol. 90-7 (1990), pp. 105-116.
Abe, T., et al., “Dynamic Behavior of Intrinsic Point Defects in FZ and CZ Silicon Crystals,” Mat. Res. Soc. Symp. Proc., vol. 262, (1992), pp. 3-13.
Abe, T., “The Formation Mechanism of Grown-In Defects in CZ Silicon Crystals Based on Thermal Gradients Measured by Thermocouples Near Growth Interfaces,” Materials Science Engineering, vol. B73, (2000), pp. 16-29.
Borionetti, G., et al., “Investigation of Low Denisty Defects in Czochralski Silicon Crystals: Their Detectability, Formation Kinetics and Influence on Gate Oxide Intergrity,” Electrochemical Society Proceedings, vol. 96-13, pp. 160-169.
De Kock, A.J.R., “Microdefects in Swirl-Free Silicon Crystals,” pp. 83-94 (source unknown), (date unknown).
De Kock, A.J.R., “The Elimination of Vacancy-Cluster Formation in Dislocation -Free Silicon Crystals,” J. of the Electrochem. Soc.: Solid-State Science and Technology, vol. 118, No. 11, (Nov. 1971), pp. 1851-1856.
De Kock, A.J.R., et al., “Effect of Growth Parameters on Formation and Elimination of Vacancy Clusters in Dislocation-Free Silicon Crystals,” Journal of Crystal Growth, vol. 22 (1974), pp. 311-320.
De Kock, A.J.R., “Point Defect Condensation in Dislocation-Free Silicon Crystals”, Semiconductor Silicon, 1977, pp. 508-520.
De Kock, A.J.R, et al., “The Effect of Doping on the Formation of Swirl Defects in Dislocation-Free Czochralski-Grown Silicon Crystals,” Journal of Crystal Growth, vol. 49, (1980) pp. 718-734.
Dornberger, E., et al., “The Impact of Dwell Time Above 900° C. During Crystal Growth on the Gate Oxide Integrity of Silicon Wafers,” Electrochemical Society Proceedings, vol. 96, No. 13, pp. 140-151.
Dornberger, E., et al., “The Dependence of Ring Like Distributed Stacking Faults on the Axial Temperature Gradient of Growing Czochralski Silicon Crystals,” Electrochemical Society Proceedings, vol. 95-4, (May/1995) pp. 294-305.
Dornberger, E., et al., “Simulation of Grown-In Voids in Czochralski Silicon Crystals,” Electrochemical Society Proceedings, vol. 97-22, pp. 40-49.
Dornberger, E., et al., “Simulation of Non-Uniform Grown-In Void Distributions in Czochralski Silicon Crystals,” Electrochemical Society Proceedings, vol. 98, vol. 1, pp. 490-503.
Dornberger, E., et al., “Defects in As-Grown Silicon and Their Evolution During Heat Treatments,” Materials Science Forum, 1997, vols. 258-263, pp. 341-346.
Eidenzon, A.M., et al., “Classification of Grown-In Microdefects in Czochralski-Grown Silicon Crystals,” Inoranic Materials, vol. 31(4), 1994, pp. 401-409.
Eidenzon, A.M., et al., “Defect-Free Silicon Crystals Grown By The Czochralski Technique,” Inorganic Materials, vol. 33, No. 3, (1997) pp. 219-225.
Eidenzon, A.M., et al., “Influence Of Growth Rate On Swirl Defects In Large Dislocation-Free Crystals Of Silicon Grown By The Czochralski Method,” Sov. Phys. Crystallogr.; vol. 30, No. 5 (1985) pp. 576-580.
Faslter, R., et al., “Intrinsic Point-Defects and Reactions in the Growth of Large Silicon Crystals,” Electrochemical Society Proceedings, vol. 98-1, pp. 468-489.
Falster, R., et al., “Intrinsic Point Defects and Their Control in Silicon Crystal Growth and Wafer Proce

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Low defect density silicon having a vacancy-dominated core... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Low defect density silicon having a vacancy-dominated core..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Low defect density silicon having a vacancy-dominated core... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3751237

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.