Low conductivity and sintering-resistant thermal barrier...

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Reexamination Certificate

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C428S633000, C428S701000, C428S702000, C428S699000, C416S24100B

Reexamination Certificate

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11282859

ABSTRACT:
A thermal barrier coating composition is provided. The composition has a base oxide, a primary stabilizer, and at least two additional cationic oxide dopants. Preferably, a pair of group A and group B defect cluster-promoting oxides is used in conjunction with the base and primary stabilizer oxides. The new thermal barrier coating is found to have significantly lower thermal conductivity and better sintering resistance. In preferred embodiments, the base oxide is selected from zirconia and hafnia. The group A and group B cluster-promoting oxide dopants preferably are selected such that the group A dopant has a smaller cationic radius than the primary stabilizer oxide, and so that the primary stabilizer oxide has a small cationic radius than that of the group B dopant.

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Dongming Zhu, et al., Thermophysical and Thermomechanical Properties of Thermal Barrier Coating Systems, pp. 623-633, Ceramic Engineering and Science Proceedings, vol. 21, 2000.
Dongming Zhu, et al., “Thermal Conductivity and Elastic Modulus Evolution of Thermal Barrier Coatings Under High Heat Flux Conditions”, pp. 175-180, Journal of Thermal Spray Technology, vol. 9(2), Jun. 2000.
Dongming Zhu et al., “Furnace Cyclic Behavior of Plasma-Sprayed Zirconia-Yttria and Multi-Component Rare Earth Oxide Doped Thermal Barrier Coatings”, pp. 1-13, 26thAnnual International Conference on Advanced Ceramics and Composites, Jan. 13-18, 2002, NASA/TM-2002-211690.
Dongming Zhu et al., “Thermal Conductivity and Stability of HfO2-Y2O3and La2Zr2O7Evaluated for 1650° C. Thermal/Environmental Barrier Coating Applications”, pp. 1-9, 105thAnnual Meeting and Exposition of the American Ceramic Society, Apr. 27-30, 2003, NASA/TM-2003-212544.
Dongming Zhu et al., “Defect Clustering and Nanophase Structure Characterization of Multicomponent Rare Earth-Oxide-Doped Zirconia-Yttria Thermal Barrier Coatings”, pp. 1-11, NASA/TM 2004-212480, Jan. 2004.
Dongming Zhu et al., “Thermal Conductivity and Sintering Behavior of Advanced Thermal Barrier Coatings”, pp. 1-10, NASA/TM-2002-211481, May 2002.

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