Cleaning compositions for solid surfaces – auxiliary compositions – Auxiliary compositions for cleaning – or processes of preparing – Textile softening or antistatic composition
Reexamination Certificate
1999-11-11
2001-01-30
Hardee, John (Department: 1751)
Cleaning compositions for solid surfaces, auxiliary compositions
Auxiliary compositions for cleaning, or processes of preparing
Textile softening or antistatic composition
C510S522000
Reexamination Certificate
active
06180594
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to low-concentration, high-viscosity aqueous fabric softeners which are in the form of aqueous emulsions or dispersions.
BACKGROUND OF THE INVENTION
As is known in the washing of textiles, fabric softeners are used in the final wash cycle. The use of fabric softeners in this fashion reduces hardening of the washed fabric which is caused by drying. The handle, i.e. feel, of textiles treated in this way, such as hand and bath towels and also underwear and bed linen, is favorably influenced.
Prior art fabric softeners typically contain cationic compounds, for example quaternary ammonium compounds, which, as well as long-chain alkyl radicals, may also contain ester or amide groups. Such fabric softeners are described for example, in U.S. Pat. Nos. 3,349,033; 3,644,203; 3,946,115; 3,997,453; 4,073,735 and 4,119,545. The above mentioned components are added to the rinse bath on their own or in mixtures with other cation-active agents or neutral substances in the form of aqueous dispersions.
Frequent use is made of ammonium compounds that contain ester bonds, as described, for example, in EP-A-0 239 910 and U.S. Pat. Nos. 3,915,867; 4,137,180 and 4,830,771.
Ester compounds based on triethanolamine, such as N-methyl, N,N-bis(beta-C
14-18
-acyloxyethyl), N-betahydroxy-ethyl-ammonium methosulfate, marketed under tradenames such as TETRANYL® AT 75 (trademark of KAO Corp.), STEPANTEX® VRH 90 (trademark of Stepan Corp.) or REWOQUAT® WE 18 (trademark of Witco Surfactants GmbH) are particularly widespread.
These esterquats have virtually replaced the previous raw materials distearyldimethylammonium chloride (DSDMAC) and imidazolinium quats throughout Europe. However, consumer requirements for these compositions vary considerably within this market.
In Northern and Central Europe, concentrates with contents of esterquats of 18-20% and a low viscosity of about 50-200 mPas are currently acceptable, while consumers in Southern and Eastern Europe prefer low concentrations of 3 to 10% by weight, in particular from 4 to 5% by weight.
The disadvantage which is criticized by consumers in the case of formulations with the low concentrations is the low viscosity and thus their consistency. Referring to the formerly used raw materials, a significantly higher viscosity is required in order to give these products a creamy, gentle appearance.
The viscosities of these products, which are desired or required to achieve the desired effect, are in the range from about 500 mPas or, preferably, above. This order of magnitude can be achieved without problem employing the traditionally used laundry softener raw materials (including DSDMAC) without the need of additional viscosity regulators. In the case of the esterquats, because of the different viscosity behavior of these raw materials, it has become difficult to achieve the desired high viscosities without additional expensive thickeners.
The disadvantages of using expensive thickeners include relatively high raw material costs and, as a result of additional stirring in and swelling of the thickeners, significantly extended production times.
Attempts already have been made to replace the partially hydrogenated fatty acids, which are used as standard in the preparation of esterquats and are based on alkanolamines and fatty acids, with completely hydrogenated fatty acids. According to experience, this should result in a significantly high viscosity. However, this is not the case to the desired extent.
It is thus even more surprising that the grade according to the present invention has unexpectedly positive viscosity behavior, which makes it possible to achieve the desired high viscosity without further additives.
SUMMARY OF THE INVENTION
One object of the present invention is to overcome the abovementioned disadvantages of conventional, low-concentration fabric softener formulations and to provide laundry fabric softeners which, in addition to good biodegradability, have a significantly improved level of good soft handle with retention of good rewetting power, yet achieve viscosities of >500 mPas without the addition of thickeners.
This object is achieved using quaternary fatty acid amino alcohol esters of triethanolamine with partially hydrogenated fatty acids in the ratio from 1:1.6 to 1:2 in alcohols or glycols.
Using processes known per se (batch and continuous processes), these products can be used to prepare stable low-viscosity fabric softener dispersions having a creamy appearance.
The present invention thus provides low-concentration, high-viscosity aqueous fabric softeners comprising from 3 to 10% by weight, preferably from 4 to 5% by weight, of at least one of the compounds of the general formula (I)
in which R is a radical of a fatty acid having from 14 to 18 carbon atoms and an iodine number in the range from 15-25, and a can be=1, 2 or 3, with the proviso that the ratio of OH groups to the radical R is=1:1.6 to 1:2.
The present invention further provides a process for the preparation of low-concentration, high-viscosity fabric softener formulations, which comprises introducing and dispersing compounds of the general formula (I) in water preheated to temperatures between 28° C. and 45° C., optionally with the co-use of solvents, dyes and perfume oils.
DETAILED DESCRIPTION OF THE INVENTION
The quaternary compounds of general formula (I) above, which are co-used according to the present invention, are prepared by processes generally known in this field, i.e. by esterification or transesterification of triethanolamine with a fatty acid and subsequent quaternization.
The fatty acid component used for the esterification or transesterification reaction is a monobasic fatty acid that is based on natural vegetable and animal oils having, in particular, 14-18 carbon atoms. Such monobasic fatty acids are conventional and are well known in this field. Illustrative examples of monobasic fatty acids include, but are not limited to: tallow fatty acids, palm fatty acids and the methyl or ethyl esters thereof.
The content of unsaturated components in these fatty acids or fatty acid esters is, if necessary, adjusted to iodine numbers between 15-25 using known catalytic hydrogenation processes, or achieved by mixing completely hydrogenated fatty components with nonhydrogenated fatty components.
The iodine number, as a measure of the average degree of saturation of a fatty acid, is the amount of iodine which is taken up by 100 g of the compound to saturate the double bonds.
According to the present invention, preference is given to partially hydrogenated tallow fatty acids and palm fatty acids having iodine numbers between 15-25. Such compounds are commercially available products and are supplied by various companies under their respective tradenames.
The esterification or transesterification reaction is carried out by processes well known in the art. In this regard, the triethanolamine is reacted with an amount of fatty acid or fatty acid ester corresponding to the desired degree of esterification under nitrogen at 160°-240° C. A catalyst, e.g. methanesulfonic acid, may be optionally used in the reaction. The water of reaction which forms and the alcohol are continuously distilled off. If necessary, it is possible to bring the reaction to completion by reducing the pressure.
The subsequent quaternization is also carried out by known processes. According to the present invention, the process preferably involves adding equimolar amounts of the quaternizing agent to the ester, optionally with co-use of a solvent such as isopropanol, ethanol, 1,2-propylene glycol and/or dipropylene glycol. Quaternization is typically carried out at 60°-90° C. with stirring and, if necessary, under pressure. The completion of the quaternization reaction is monitored by checking the overall amine number.
Examples of quaternizing agents which can be co-used in the present invention are short-chain dialkyl phosphates and sulfates, such as diethyl sulfate, dimethyl phosphate, diethyl phosphate and short-chain halogenated
Fender Michael
Kohle Hans-Jurgen
Schussler Simone
Hardee John
Scully Scott Murphy & Presser
Witco Surfactants GmbH
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