Low benzene butadiene polymerization

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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5263404, 526903, C08F 460, C08F 206

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active

042424780

ABSTRACT:
A process is provided for the polymerization of butadiene-1,3 to yield a high cis-1,4-polybutadiene in which the diluent for the polymerization is a mixture of cyclohexane and either or both of benzene and butene-1, wherein the amount of benzene is markedly reduced in comparison with that generally used. The polybutadiene may be used in the manufacture of tires and in impact polystyrene.

REFERENCES:
patent: 3068180 (1962-12-01), van Amerongen
patent: 3845029 (1974-10-01), Throckmorton
patent: 3962375 (1976-06-01), Throckmorton
patent: 3966697 (1976-06-01), Kampf

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