Long life reference electrode

Chemistry: electrical and wave energy – Apparatus – Electrolytic

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Details

204435, G01N 2728, G01N 2730, G01N 2740

Patent

active

048183660

ABSTRACT:
An external, reference electrode is provided for long term use with a high temperature, high pressure system. The electrode is arranged in a vertical, electrically insulative tube with an upper portion serving as an electrolyte reservior and a lower portion in electrolytic communication with the system to be monitored. The lower end portion includes a flow restriction such as a porous plug to limit the electrolyte release into the system. A piston equalized to the system pressure is fitted into the upper portion of the tube to impart a small incremental pressure to the electrolyte. The piston is selected of suitable size and weight to cause only a slight flow of electrolyte through the porous plug into the high pressure system. This prevents contamination of the electrolyte but is of such small flow rate that operating intervals of a month or more can be achieved.

REFERENCES:
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patent: 4414093 (1983-11-01), Redey et al.
patent: 4659451 (1987-04-01), Fujita et al.
McDonald et al., "External Reference Electrodes for Use in High Temperature Aqueous System", J. of Electrochemical Soc., pp. 908-911, Jun., 1979.
McDonald, "Reference Electrodes for High Temperature Aqueous Systems-a Review & Assessment", Corrosion, pp. 75-84, NACE, 1978.
Nagy et al., "Palladium/Hydrogen Membrane Electrode for High Temperature/High Pressure Aqueous Solutions", J. of the Electrochemical Soc., vol. 33, No. 11, Nov. 1986, Reprint, pp. 2232-2235.

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