Long chain N,N,-dialkylhydroxylamines and stabilized composition

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

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C08K 532

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active

047821051

ABSTRACT:
Long chain N,N-dialkylhydroxylamines represent particularly valuable stabilizers for a number of polymer substrates. Their particular value is seen in their high temperature processing stabilization of poly(arylene sulfide), such as poly(phenylene sulfide), PPS, and of selected unsaturated elastomers used to modify thermoplastics. PPS is processed at elevated temperatures (300.degree. to 425.degree. C.) at which temperatures it crosslinks readily. Process stabilizers can extend the time to crosslinking and hence the processibility of the PPS. Long chain N,N-dialkylhydroxylamines are very effective process stabilizers for PPS being far superior to phenolic antioxidants, phosphites or amines. The hydroxylamine derived from di(hydrogenated tallow)amine is particularly useful for this purpose.

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