Long chain branching in polyolefins from ziegler-natta catalysts

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502103, 502109, 502110, 502117, 502134, 526125, 526153, 526352, C08F 462, C08F 464, C08F 468, C08F 470

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active

045006482

ABSTRACT:
Generally, linear polyethylene containing long chain branching is obtained by polymerizing ethylene in the presence of a catalyst comprising a transition metal compound such as titanium chloride, an organoaluminum compound represented by the formula R.sub.1 R.sub.2 AlR.sub.p wherein R.sub.1 & R.sub.2 are the same or different hydrocarbyl groups having from 1 to 18 carbon atoms and R.sub.p is a polymeric hydrocarbyl group containing long chain branching and an aluminum alkyl cocatalyst.

REFERENCES:
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patent: 3910870 (1975-10-01), Lutze et al.
patent: 3910979 (1975-10-01), Eidt
patent: 4027089 (1977-05-01), Aishima et al.
patent: 4170603 (1979-10-01), Fannin
patent: 4187197 (1980-02-01), Kabanov et al.
Organoaluminum Compounds, Mole et al., pub. by Elsevier Oub. Co., New York, (1972), p. 67.

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