Living polymerization method

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526172, 526189, 526192, 526204, 526270, 526273, 526328, C08F 444, C08F 406, C08F 452, C08F 400, C08F12400, C08F12012

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053289706

ABSTRACT:
A living polymerization method in which an organic aluminum compound having a bulky substituent group is used as a cocatalyst in the living polymerization of a (meth)acrylic acid ester, an epoxide or a lactone in the presence of a metal porphyrin complex as a polymerization initiator.

REFERENCES:
patent: 4760117 (1988-07-01), Evans et al.
K. Shimasaki, T. Aida, and S. Inoue, Macromolecules 20, 3076-3080, 1987.
T. Adachi, H. Sugimoto, T. Aida, and S. Inoue, Macromolecules 25, 2280-2281, 1987.
S. Asano, T. Aida, and S. Inoue, J. Chem. Soc., Chem. Commun. pp. 1148-1149, 1985.

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