Lithium secondary cell

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

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429218, H01M 448

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active

050155474

ABSTRACT:
A chargeable lithium secondary cell comprising a positive electrode composed mainly of vanadium pentaoxide, a negative electrode of a compound of lithium with niobium pentaoxide and an electrolyte of an organic solvent in which a lithium salt is dissolved, wherein resistance to overdischarge is obtained by a constitution that the molar ratio of the niobium pentaoxide to vanadium pentaoxide is from not less than 0.5 to not more than 1 and the molar ratio of the total litium contained in the positive and negative electrodes to vanadium pentaoxide is from not less than 1.1 to not more than 2.

REFERENCES:
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patent: 4751158 (1988-06-01), Uchiyama et al.
patent: 4786499 (1988-11-01), Slane et al.
Denki Kagaku 50, No. 8 (1982).
Electrochimica Acta, vol. 28 No. 1, Jan. 1983, pp. 17-22, Pergamon Press Ltd., Oxford, GB; N. Kumagai et al.: "Structural Changes of Nb205 and V205 as Rechargeable Cathodes for Lithium Battery".
Extended Abstracts, vol. 86-2, "Fall Meeting San Diego, Calif., 19th-24th Oct. 1986", pp. 28-29, Princeton, NJ, U.S.; J. J. Auborn et al.: Lithium Intercalation Cells without Metallic Lithium: MoO2/LiCoO2 and WO2/LiCoO2.
Patent Abstracts of Japan, vol. 6, No. 28 (E-95) [906], 19th Feb. 1982; & JP-A-56 147 368 (Yuasa Denchi K.K.) 16-11-1981.
Journal of Power Sources, vol. 20, Nos. 3-4, Jul. 1987, pp. 187-192, Lesevier Sequoia, Lausanne, CH: Y. Muranishi et al.: "Insertion of Lithium into Vanadium Molybdenum Oxides".

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