Lithium secondary battery

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

Reexamination Certificate

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Details

C429S218100, C205S059000, C252S182100

Reexamination Certificate

active

06613477

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to a lithium secondary battery having a positive electrode, a negative electrode and a non-aqueous electrolyte.
BACKGROUND OF THE INVENTION
A secondary battery, especially, a lithium secondary battery has lately been attracting attention as an operating power source for portable electronic equipment that can be miniaturized, is highly efficient and is cordless. A lithium secondary battery contains a positive electrode having a positive electrode active material, a negative electrode having a negative electrode active material and a non-aqueous electrolyte.
The most common and practical lithium secondary battery has a carbon material, for example, graphite or the like, as a negative electrode active material, and crystalline LiCoO
2
as a positive electrode active material. A lithium secondary battery having a high voltage, i.e., 4V, and high energy density can be provided because crystalline LiCoO
2
has a high voltage level.
However, reduction of consumption of power has been recently required for electronic equipment. Operating voltages of electric circuits have been gradually reduced. Therefore, a lithium battery having high discharge capacity density is required more than one having a high discharge voltage.
OBJECT OF THE INVENTION
An object of the present invention is to provide a lithium secondary battery which has higher capacity density per volume and per weight.
SUMMARY OF THE INVENTION
The present invention provides a lithium secondary battery having positive and negative electrodes and a non-aqueous electrolyte, wherein the positive electrode contains Li—Bi alloy or Li—Sb alloy as an active material.


REFERENCES:
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patent: 6322930 (2001-11-01), Yoshimura et al.
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patent: 11-54117 (1999-02-01), None
Besenhard, J. O. et al.; “Reversibles Elektrochemisches Legieren von Metallen der V. Hauptgruppe in Organischen Li+-Lösungen”;Electrochimica Acta; vol. 20, pp. 513-517; 1975, No Month available.
Chemical Abstracts, No. 83(18)154522x; “Reversible Electrochemical Alloying of Group V Metals in Orgaic Solutions Containing Lithium (1+)”, No date available.
Demidov, A. I. et al.; “Alloy Formation During Lithium Deposition on Antimony and Bismuth Cathodes”;Elektrokhimiya; vol. 19, pp. 1695-1699; 1983, No month available.
Chemical Abstracts, No. 100(8)58704g; “Alloy Formation During Lithium Deposition on Antimony Bismuth Cathodes”, No date available.
Wang, J. et al.; “Behavior of Some Binary Lithium Alloys as Negative Electrodes in Organic Solvent-Based Electrolytes”;Journal of the ElectrochemicalSociety: Electrochemical Science and Technology; vol. 133, No. 3, pp. 457-460; Mar. 1986.

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