Lithium/organosulfur redox cell having protective solid electrol

Chemistry: electrical current producing apparatus – product – and – Fluid active material or two-fluid electrolyte combination... – Active material in molten state

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429213, 296235, H01M 460

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active

049179748

ABSTRACT:
A lithium/organosulfur redox cell is disclosed which comprises a solid lium anode, a liquid organosulfur cathode, and a barrier layer formed adjacent a surface of the solid lithium anode facing the liquid organosulfur cathode consisting of a reaction product of the lithium anode with the organosulfur cathode. The organosulfur cathode comprises a material having the formula (R(S).sub.y).sub.N where y=1 to 6, n=2 to 20 and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, nitrogen, or fluorine atoms associated with the chain when R comprises an aliphatic chain, wherein the linear chain may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon.

REFERENCES:
patent: Re31489 (1984-01-01), Sekido et al.
patent: 3957533 (1976-05-01), Mess et al.
patent: 4237200 (1980-12-01), Weddiga
patent: 4317874 (1982-03-01), Joshi et al.
patent: 4465745 (1984-08-01), Akridge
patent: 4833048 (1989-05-01), DeJonghe et al.

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