Lithium ion battery comprising nanomaterials

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

Reexamination Certificate

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C429S231400, C429S233000, C423S447100, C423S44500R, C423S594400, C423S594600

Reexamination Certificate

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07060390

ABSTRACT:
A lithium ion battery includes a cathode (10) having a plurality of nanoparticles of lithium doped transition metal alloy oxides represented by the formula LixCoyNizO2, an anode (20) having at least one carbon nanotube array (22), an electrolyte, and a membrane (30) separating the anode from the cathode. The carbon nanotube array includes a plurality of multi-walled carbon nanotubes (23). Preferably, an average diameter of an outermost wall of the multi-walled carbon nanotubes is in the range from 10 to 100 nanometers, and a pitch between adjacent multi-walled carbon nanotubes is in the range from 20 to 500 nanometers. In the carbon nanotube array, the lithium ions are able to intercalate not only inside the multi-walled carbon nanotubes, but also in the interstices between adjacent multi-walled carbon nanotubes. Thus a density of intercalation of the carbon nanotube array is significantly higher than that of graphite.

REFERENCES:
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patent: 2003/0054249 (2003-03-01), Yamamoto et al.
patent: 2003/0147801 (2003-08-01), Someya et al.
Frackowiak et al. “Electrochemical storage of lithium multiwalled carbon nanotubes” Pergamon, Carbon 37, (1999), pp. 61-69.
Sang-Cheol Han et al. “Effect of Multiwalled Carbon Nanotubes on Electrochemical Properties of Lithium/Sulfur Rechargeable Batteries”; Journal of The Electrochemical Society, 150 (7), Jul. 1, 2003, pp. A889-A893.
Jae-hee Han et al. “Growth and emission characteristics of vertically well-aligned carbon nanotubes grown on glass substrate by hot filament plasma-enhanced chemical vapor deposition”; Journal of Applied Physics, 88 (12), Dec. 15, 2000, pp. 7363-7365.

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