Liquid phase process for the manufacture of methyl tertiary ethe

Details Liquid phase process for the manufacture of methyl tertiary ethe Liquid phase process for the manufacture of methyl tertiary ethe

1979-09-04

1981-03-31

Mars, Howard T.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

C07C 4106

Patent

active

042595339

ABSTRACT:
The present invention is a homogeneous liquid phase process for the preparation of methyl-t-butyl ether by reacting isobutylene and methanol in the presence of a heteropoly acid of molybdenum, tungsten or vanadium. Other tertiary ethers may be obtained by substituting a different tertiary olefin for isobutylene, e.g. t-amyl methyl ether from 2-methylbutene-2 and methanol.

REFERENCES:
patent: 2162913 (1939-06-01), Eversole et al.
patent: 2591493 (1952-04-01), Arnold et al.
patent: 2702232 (1955-02-01), Arnold et al.
patent: 3135807 (1964-06-01), Grasselli et al.
patent: 3285977 (1966-11-01), Henke et al.

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