Liquid phase oxidation of unsaturated aliphatic aldehydes to uns

Details Liquid phase oxidation of unsaturated aliphatic aldehydes to uns Liquid phase oxidation of unsaturated aliphatic aldehydes to uns

1977-01-12

1978-06-27

Garner, Vivian

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260526N, 260539R, C07C 5132, C07C 5704, C07C 5706, C07C 5708

Patent

active

040975231

ABSTRACT:
A process for the liquid phase oxidation of .alpha.,.beta.-unsaturated aldehydes, and the in situ decomposition of unsaturated intermediate peroxy (peroxide) compounds formed during oxidation, to the corresponding unsaturated aliphatic acid which comprises passing oxygen or an oxygen-containing gas through an inert solvent solution of the aldehyde at a suitable temperature and pressure in the presence of a catalytic amount of a thallium salt. The solvents employed may be mixed with water forming a heterogeneous solvent system.

REFERENCES:
patent: 3703548 (1972-11-01), Honda et al.

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