Liquid phase catalytic co-oxidation process

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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562408, 562503, 562504, 562543, 562508, 562509, 562544, 562548, 560 51, 560 55, 560 77, 560121, 560127, 560190, 560243, 568431, C09F 702, C11C 300

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043316085

ABSTRACT:
Unsaturated compounds having at least 4 carbon atoms, including unsaturated alicyclic compounds having at least 4 carbon atoms, unsaturated aliphatic compounds having at least one carbon-carbon unsaturated bond and having at least 4 carbon atoms and unsaturated aromatic compounds having at least one carbon-carbon unsaturated bond in the branched chain thereof and (ii) aldehydes or ketones having at least 4 carbon atoms are catalytically co-oxidized with an oxygen-containing gas in a liquid phase to form a cleaveged product or products of unsaturated bond of the unsaturated compounds at a high yield. This co-oxidation reaction is carried out in the presence of a heavy metal containing iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum, copper, silver, chromium, molybdenum, tungsten, manganese and rhenium and the compounds thereof.

REFERENCES:
patent: 3409649 (1968-11-01), Keblys
patent: 3658896 (1972-04-01), Washecheck
patent: 3668257 (1972-06-01), Schaeffer
patent: 3821259 (1974-06-01), Bljumberg et al.

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