Liquid methylene diphenyl diisocyanate

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having at least one -n=c=x group as well as...

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528 45, 528 49, 528 55, 528 67, 25218222, 560 27, C08G 1872

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active

053190548

ABSTRACT:
The present invention relates to a process for the production of a allophanate-modified MDI which is a storage stable liquid at 25.degree. C. comprising (A) reacting (i) one equivalent of a diisocyanate and (ii) one equivalent of an aliphatic alcohol containing from 1 to about 36 carbon atoms or aromatic alcohol containing from 6 to 18 carbon atoms to form a diurethane of the diisocyanate, (B) reacting the product of (A) with 4,4'-diphenylmethane diisocyanate containing from 2 to 60% by weight 2,4'-MDI and less than 6% by weight of the 2,2'-MDI, in an amount sufficient to provide an allophanate having an isocyanate group content of about 12.0 to 30.0%.

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