Liquid hydrocarbon synthesis using supported ruthenium catalysts

Details Liquid hydrocarbon synthesis using supported ruthenium catalysts Liquid hydrocarbon synthesis using supported ruthenium catalysts

1983-04-28

1984-10-16

Mars, Howard T.

Chemistry: fischer-tropsch processes; or purification or recover

Group viii metal containing catalyst utilized for the...

C07C 104

Patent

active

044775954

ABSTRACT:
Selective production of C.sub.5 -C.sub.40 hydrocarbons containing C.sub.5 -C.sub.20 hydrocarbons having a high paraffins content, i.e., for producing gasoline and diesel fuel and useful as a chemical feedstock, is achieved by contacting H.sub.2 /CO mixtures with supported ruthenium catalysts under conditions including elevated temperature and ratios of gas hourly space velocity/pressure below about 24,000 v/v/hr/MPaA to effect percent CO conversions at least about 20%. The ruthenium catalyst support contains a titanium oxide, niobium oxide, vanadium oxide or tantalum oxide and C.sub.5 -C.sub.40 hydrocarbons can be selectively obtained in about 60-90 weight percent of total hydrocarbon products.

REFERENCES:
patent: 2632014 (1953-03-01), Gresham
patent: 3922235 (1975-11-01), DeLuca et al.
patent: 4042614 (1977-08-01), Vannice et al.
patent: 4171320 (1979-10-01), Vannice et al.
patent: 4199522 (1980-04-01), Murchison et al.
Dry, Advances in Fischer-Tropsch Chemistry, Ind. Eng. Chem. Prod. Res. Dev., vol. 15, No. 4, 1976, pp. 282-286.
Karn et al., I & EC Product Res. & Dev., 4, 265, (1965).
Pichler, Brenns-Chemie, 19, 226, (1938).
Pichler et al., Brenns-Chemie, 21, 247, 273, 285, (1940).
Vannice et al., III, Talk entitled, "The Difference of the Support in CO Hydrogenation Reactions", Jun. 1980.
Kugler, Talk entitled, "Synthesis of Light Olefins from CO and H.sub.2 ", Aug. 24-29, (1980).
J. Am. Chem. Soc., 99, (8), pp. 2796-2797.
J. of Catalysis, vol. 37, pp. 449-461, (1975), "The Catalytic Synthesis of Hydrocarbons from H.sub.2 /CO Mixtures Over the Group VIII Metals", by M. A. Vannice.
J. of Catalysis, 63, pp. 255-260, (1980), "The Influence of the Support in the Catalytic Behavior of Ruthenium in CO/H.sub.2 Synthesis Reactions", by M. A. Vannice and R. C. Garten.
"The Influence of Support on K Promotion of Ru for the Fischer-Tropsch Synthesis", by C. H. Yang et al., in ACS Div. Fuel Chem., Preprint 27, vol. 3-4, 189th ACS Nat'l Mtg., Kansas City, 1982.
"C.sub.1 Chemistry/Hyrogenation of Carbon Monoxide on Supported Ruthenium Catalysts", by T. Fukushima et al., in Nippon Kagaku Kaish.
J. of Catalysis, vol. 56, pp. 236-248, (1979), "Metal-Support Effects on the Activity and Selectivity of Ni Catalysts in CO/H.sub.2 Synthesis Reactions", by M. A. Vannice and R. L. Garten.
Support Effects in the Ruthenium-Catalyzed Hydroformylation of Carbon Monoxide, by S. R. Morris et al., in the publication "Metal-Support and Metal-Additive Effects in Catalysis", pp. 247-254.

Affiliated with

Also associated with

Rating

Liquid hydrocarbon synthesis using supported ruthenium catalysts does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Liquid hydrocarbon synthesis using supported ruthenium catalysts, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Liquid hydrocarbon synthesis using supported ruthenium catalysts will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1945887