Liquid crystalline ethane derivatives, their preparation and the

Compositions – Liquid crystal compositions – Containing nonsteryl liquid crystalline compound of...

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2522996, 25229962, 25229963, 25229966, 350350R, 350350S, 544242, 544294, 544296, 544298, 544316, 544335, 549370, 549372, 549373, 558 17, 558 18, 558 19, C09K 1934, C09K 1930, C09K 1914, C07C16104, C07D31906, C07D23926

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048491306

ABSTRACT:
Liquid crystalline ethane derivatives by the described method in order to form liquid crystalline compositions with known liquid crystalline compounds have a general formula I: ##STR1## wherein, if ring A idicates a 1,4-substituted benzene ring, then ring B indicates 1.4-substituted benzene ring or 1.4-trans-substituted cyclohexane ring or 1.4-substituted bicyclo[2,2,2]octane ring or 2.5-substituted pyrimidine ring or 2.5-substituted 1.3- dioxane ring, or if ring B indicates a 1.4-substituted benzene ring, then A indicates 1.4-trans-substituted cyclohexane ring or 1.4-substituted bicylo[2,2,2]octane ring or 2.5-substituted pyrimidine ring or 2.5-substituted 1.3-dioxane ring, and R indicates a normal alkyl chain C.sub.n H.sub.2n+1 or a non-branched alkoxy group C.sub.n H.sub.2n+1 O or an alkylcarboxylic group C.sub.n H.sub.2n+1 COO or an alkyl carbonato group C.sub.n H.sub.2n+1 OCOO or a branched alkyl chain CH.sub.3 --CH.sub.2 --CH(CH.sub.3)--(CH.sub.2).sub.k -- or a branched alkoxy group CH.sub.3 --CH.sub.2 --CH(CH.sub.3)--(CH.sub.2).sub.k --O, where n is an integer number and assumes values from 1 to 12, k is an integer number and assumes values from 1 to 3 and l and m assume values 1 or 0 fulfilling the condition that l+m>0, and if ring A denotes 1.4-disubstituted bicyclo[2,2,2] octane ring also l+m=0. Liquid crystalline compositions containing the compound of formula I are characterized by low viscosity and are applied in displays.

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