Liquid acid alkylation catalyst and isoparaffin:olefin alkylatio

Chemistry of hydrocarbon compounds – Saturated compound synthesis – By condensation of a paraffin molecule with an olefin-acting...

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585723, 585730, 502150, 502170, C07C 260, C07C 262, B01J 2702

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active

052025187

ABSTRACT:
The invention provides an acid catalyst composition for alkylation of an isoparaffin with an olefin comprising from about 10 to about 90 percent of at least one acid selected from the group consisting of hydrofluoric acid and the halogen-substituted sulfonic acids, together with from about 10 to about 90 weight percent of a mono-, di-, or tri-carboxylic acid substituted member selected from the group consisting of alkanes, aromatics, haloalkanes, and haloaromatics having from about 1 to about 30 carbon atoms.

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"Alkylation of Isobutane with C.sub.4 Olefins", 27 Ind. Eng. Chem. Res., 381-397, (1988).
Handbook of Petroleum Refining Processes, 23-28 (R. A. Meyers, ed., 1986).

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