Liquefaction with microencapsulated catalysts

Mineral oils: processes and products – Phenolic or toxic oils

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208 10, 502159, C10G 100

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active

045184780

ABSTRACT:
A method of dispersing a liquefaction catalyst within coal or other carbonaceous solids involves providing a suspension in oil of microcapsules containing the catalyst. An aqueous solution of a catalytic metal salt is emulsified in the water-immiscible oil and the resulting minute droplets microencapsulated in polymeric shells by interfacial polycondensation. The catalyst is subsequently blended and dispersed throughout the powdered carbonaceous material to be liquefied. At liquefaction temperatures the polymeric microcapsules are destroyed and the catalyst converted to minute crystallites in intimate contact with the carbonaceous material.

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Chien et al, "Coal Liquefaction with Encapsulated Catalyst", I&EC Process Design & Development, vol. 22, pp. 660-662, ACS, Oct. 1983.

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