Liquefaction process for solid carbonaceous materials containing

Mineral oils: processes and products – Phenolic or toxic oils

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C10G 104

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043326676

ABSTRACT:
An improved liquefaction process wherein wall scale and particulate agglomeration during the liquefaction of solid carbonaceous materials containing alkaline earth metal humates is reduced and/or eliminated by subjecting the solid carbonaceous materials to controlled cyclic cavitation during liquefaction. It is important that the solid carbonaceous material be slurried in a suitable solvent or diluent during liquefaction. The cyclic cavitation may be imparted via pressure cycling, cyclic agitation and the like. When pressure cycling or the like is employed an amplitude equivalent to at least 25 psia is required to effectively remove scale from the liquefaction vessel walls.

REFERENCES:
patent: 2722498 (1955-11-01), Morrell et al.
patent: 3503865 (1970-03-01), Stone
patent: 3808119 (1974-04-01), Bull et al.
patent: 4108759 (1978-08-01), Young
patent: 4121910 (1978-10-01), Stambaugh
EDS Coal Liquefaction Process Development Phase III A, Monthly Technical Progress Report for Dec. 31, 1976, Exxon Research and Engineering Co., published Feb. 1977, p. 8.
EDS Coal Liquefaction Process Development Phase III A, Monthly Technical Progress Report for Jan.-Jul. 31, 1976, Exxon Res. & Eng. Co., published Jul. 1977.
EDS Coal Liquefaction Process Development Phase III A, Annual Technical Progress Report for Jan.-Dec. 31, 1976, Exxon Res. & Eng. Co., submitted Dec. 1977.
EDS Liquefaction Process Development Phase III A, Quarterly Technical Progress Report for Jan.-Mar. 31, 1977, Exxon Res. & Eng. Co., submitted Dec. 1977.

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