Linear polymers from blocked vinyl biphenyl compounds

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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430 33, 526270, 526289, 5262929, 526291, 526314, 526326, 568642, 568643, C08F 2804, C08F 2400, C08F 1622

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active

044120508

ABSTRACT:
The present invention relates to vinyl biphenyl compounds of the formula ##STR1## wherein one of R.sup.1 and R.sup.2 is vinyl and the other is hydrogen, and the cyclic moiety A is a -2,5-, -2,3-, or -3,4- di-OR-1-phenyl moiety wherein R is a hydroxy-protecting group, polymers prepared therefrom, and methods of preparation thereof. The subject vinyl biphenyls can be polymerized and the resultant polymers deblocked to remove the R groups and provide the corresponding polymeric dihydroxybiphenyls which can be employed as redox polymers.

REFERENCES:
patent: 2710801 (1955-06-01), Minsk
patent: 2735837 (1956-02-01), Minsk
patent: 3267073 (1966-08-01), Kun
patent: 4054676 (1977-10-01), Weinshenker
Rao, M. L. B. et al., Chem. and Indust. (London), 1961, p. 145.
Cassidy, H. G. et al., Oxidation-Reduction Polymers, Interscience Publ., New York, 1965, pp. 43, 44.
Manecke, G. et al., Makromol. Chem., 123 (1969), pp. 223-232.

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