Linear polyesters containing isocyanurate rings and processes fo

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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C08G 6368

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active

039621928

ABSTRACT:
Phenylisocyanurate is reacted with ethyl-chloroacetate in an inert solvent at 25.degree.C. to 150.degree.C. to produce crystalline 1,3-bis(carbethoxymethylene)-5-phenylisocyanurate. The 1,3-bis(carbethoxymethylene)-5-phenylisocyanurate is then heated with a mineral acid to produce crystalline 1,3-bis(carboxymethylene)-5-phenylisocyanurate. A novel polyester of the formula ##SPC1##
Is made wherein N=1, M is a diol having at least two carbon atoms, and X is a whole number greater than 1 by condensing 1,3-bis(carboxymethylene)-5-phenylisocyanurate with a polyol such as 1,4-butanediol.

REFERENCES:
patent: 3235553 (1966-02-01), Sadle
patent: 3279940 (1966-10-01), Francis et al.
patent: 3331839 (1967-07-01), Little
patent: 3370045 (1968-02-01), Sadle
patent: 3407200 (1968-10-01), Little et al.
patent: 3485833 (1969-12-01), Sadle

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