Linear alxylbenzene formation using low temperature ionic liquid

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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585456, 585459, 585461, 585462, 585469, 556 2, 556138, C07C 264

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058248323

ABSTRACT:
A low temperature molten ionic liquid composition comprising a mixture of a metal halide and an alkyl-containing amine hydrohalide salt can be used in linear alkylbenzene formation. The metal halide is a covalently bonded metal halide which can contain a metal selected from the group comprised of aluminum, gallium, iron, copper, zinc, and indium, and is most preferably aluminum trichloride. The alkyl-containing amine hydrohalide salt may contain up to three alkyl groups, which are preferably lower alkyl, such as methyl and ethyl.

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Derwent Patent Abstract 89-272569/38 (1989).
M.F. Cox et al., "Effect of LAB Composition on LAS Performance", INFORM, vol. 8, No. 1 (Jan. 1997), pp. 19-24.
M. Matsui et al., "Aluminum Chloride-Tetraalkylammonium Halide Complex as a Novel Catalyst in Friedel-Crafts Alkylation. Direct Construction of the Chroman Structure from 1,3-Diene", Bull. Chem. Soc. Jpn., 68, 2663-2668 (1995). No month available.

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