Limited dispersity epitaxially sensitized ultrathin tabular grai

Radiation imagery chemistry: process – composition – or product th – Radiation sensitive product – Silver compound sensitizer containing

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430569, 430637, G03C 1035, G03C 1043

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active

057260079

ABSTRACT:
A photographic emulsion is disclosed comprised of coprecipitated radiation-sensitive silver halide grains containing greater than 70 mole percent bromide, based on silver, and exhibiting a coefficient of variation of less than 30 percent. Greater than 90 percent of total projected area of the grains is accounted for by tabular grains having {111} major faces, exhibiting a thickness of less than 0.07 .mu.m, and having latent image forming silver salt epitaxy chemical sensitization sites on their surfaces, and a dispersing medium that contains a grain dispersity reducing concentration of a polyalkylene oxide block copolymer surfactant comprised of two terminal lipophilic alkylene oxide block units linked by a hydrophilic alkylene oxide block unit accounting for from 4 to 96 percent of the molecular weight of the polymer. The emulsions offer unexpectedly low levels of minimum density and can be more easily manufactured as compared to conventional ultrathin tabular grain emulsions with comparably limited grain dispersity.

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