Compositions: coating or plastic – Coating or plastic compositions – Inorganic settable ingredient containing
Reexamination Certificate
2003-06-04
2004-02-10
Green, Anthony J. (Department: 1755)
Compositions: coating or plastic
Coating or plastic compositions
Inorganic settable ingredient containing
C106S793000, C106S811000, C106S681000, C166S292000, C166S293000, C405S266000, C405S267000, C507S140000, C507S269000
Reexamination Certificate
active
06689208
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to subterranean cementing operations, and more particularly, to lightweight cement compositions, and methods of using such compositions in subterranean well cementing operations.
2. Description of the Prior Art
Hydraulic cement compositions are commonly utilized in subterranean operations, particularly subterranean well completion and remedial operations. For example, hydraulic cement compositions are used in primary cementing operations whereby pipe strings such as casings and liners are cemented in well bores. In performing primary cementing, hydraulic cement compositions are pumped into the annular space between the walls of a well bore and the exterior surface of the pipe string disposed therein. The cement composition is permitted to set in the annular space, thereby forming an annular sheath of hardened substantially impermeable cement therein that substantially supports and positions the pipe string in the well bore and bonds the exterior surfaces of the pipe string to the walls of the well bore. Hydraulic cement compositions also are used in remedial cementing operations such as plugging highly permeable zones or fractures in well bores, plugging cracks and holes in pipe strings, and the like.
Subterranean formations transversed by well bores are often weak and extensively fractured. In some cases, the formation may be unable to withstand the hydrostatic head pressure normally associated with cement being pumped in the formation. In such cases, the hydrostatic pressure may be sufficient to force cement into the extensive fractures of the formation, which may result in a significant loss of cement into the formation during cementing operations. This loss of cement composition is problematic because, inter alia, less of the cement composition will remain in the annular space to form the protective sheath that bonds the pipe string to the walls of the well bore. Accordingly, fracturing the subterranean formation while cementing is of great concern.
SUMMARY OF THE INVENTION
The present invention provides lightweight cement compositions, and methods for cementing in a subterranean formation using such cement compositions.
One method of the present invention comprises providing a cement composition comprising vitrified shale, hydrated lime, and water; placing this cement composition in a subterranean formation; and allowing the cement composition to set therein.
One embodiment of the cement compositions of the present invention comprises vitrified shale, hydrated lime, and water. Optionally, other additives suitable for cement compositions may be added to the cement compositions of the present invention.
The objects, features and advantages of the present invention will be readily apparent to those skilled in the art upon a reading of the description of the preferred embodiments which follows.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
The present invention provides lightweight cement compositions and methods of utilizing these cement compositions in subterranean cementing operations. While the compositions and methods of the present invention are useful in a variety of subterranean applications, they are particularly useful in well completion and remedial operations, including primary cementing, e.g., cementing casings and liners in well bores, including those in multi-lateral subterranean wells.
The improved cement compositions of the present invention generally comprise: an unhydrated cement comprising hydrated lime and vitrified shale; and water sufficient to make the cement composition a slurry. As referred to herein, hydrated lime will be understood to mean calcium hydroxide (Ca(OH)
2
). Other additives suitable for use in conjunction with subterranean cementing operations also may be added to these cement compositions if desired. Typically, the cement compositions of the present invention have a density in the range of from about 4 lb/gallon to about 20 lb/gallon. In certain preferred embodiments, the cement compositions of the present invention have a density in the range of from about 8 lb/gallon to about 17 lb/gallon.
The hydrated lime is present in the cement compositions of the present invention in an amount sufficient to form calcium silicate hydrates upon reaction with a source of water and a source of vitrified shale. Calcium silicate hydrates, inter alia, lend strength to cement compositions. More particularly, the hydrated lime is present in the cement composition in an amount in the range of from about 5% to about 20% percent by weight of the unhydrated cement. In certain preferred embodiments, the hydrated lime is present in the cement composition in an amount in the range of from about 10% to about 15% by weight of the unhydrated cement. An example of a suitable hydrated lime is commercially available from Continental Lime, Inc., of Salt Lake City, Utah.
The vitrified shale is present in the cement compositions of the present invention in an amount sufficient to form calcium silicate hydrates upon reaction with a source of water and a source of hydrated lime. More particularly, the vitrified shale is present in the cement composition in an amount in the range of from about 80% to about 95% by weight of the unhydrated cement. In certain preferred embodiments, the vitrified shale is present in the cement composition in an amount in the range of from about 85% to about 90% by weight of the unhydrated cement. An example of a suitable vitrified shale is commercially available under the tradename “PRESSUR-SEAL® FINE LCM” from TXI Energy Services, Inc., in Houston, Tex.
The water utilized in the cement compositions of the present invention can be fresh water, salt water (e.g., water containing one or more salts dissolved therein), brine (e.g., saturated salt water), or seawater. Generally, the water can be from any source provided that it does not contain an excess of compounds, e.g., dissolved organics, that may adversely affect other components in the cement composition. The water may be present in an amount sufficient to form a pumpable slurry. More particularly, the water is present in the cement compositions in an amount in the range of from about 40% to about 90% by weight of the unhydrated cement. In certain preferred embodiments, the water is present in the cement compositions in an amount in the range of from about 40% to about 80% by weight of the unhydrated cement.
Optionally, the cement compositions of the present invention may comprise a means to reduce their densities, including, for example, an expanding additive, microspheres, or the like. For example, the cement compositions of the present invention may be foamed cement compositions wherein an expanding additive that produces a gas within the cement composition has been added. If the cement composition is foamed, foaming agents and/or foam stabilizing agents, or mixtures thereof, may be included in the cement composition in order, inter alia, to facilitate the foaming and/or enhance the cement composition's stability. The foaming agent and/or foam stabilizing agent is generally present in the cement composition in an amount sufficient to provide a stable foamed cement composition. One of ordinary skill in the art with the benefit of this disclosure will recognize the appropriate type of foaming agent and/or foam stabilizing agent for use in a particular application, along with the ranges in which such agent or agents should be incorporated. One of ordinary skill in the art with the benefit of this disclosure will also recognize the proper amount of an expanding additive to use in order to provide a foamed cement composition having a desired density.
Another example of a suitable means to reduce the density of the cement compositions of the present invention is one that employs microspheres. Because the microspheres have specific gravities below about 1.0, their inclusion in a cement composition acts to reduce the overall cement composition's density. Any microspheres that are compatible with a subte
Green Anthony J.
Halliburton Energy Service,s Inc.
Jordan Carey C.
Roddy Craig W.
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