Lightly crosslinked polyimides

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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528125, 528126, 528128, 528170, 528172, 528174, 528175, 528185, 528186, 528188, 528220, 528226, 528229, 528322, 528342, 528345, 528348, 528350, 528351, 528352, 528353, 525422, 525426, C08G 7310, C08G 6926, C08G 802

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active

051752344

ABSTRACT:
Polyimide oligomers include (1) linear, monofunctional crosslinking oligomers prepared by condensing a monoanhydride end cap with a diamine that includes alternating ether and "Sulfone" (--SO.sub.2 --, --S--, --CO--, --(CF.sub.3).sub.2 C--, or --(CH.sub.3).sub.2 C--) linkages connecting alternating aromatic radicals and with a dianhydride (or dianhydride mixture), particularly the unsaturated, aliphatic dianhydride commonly known as MCTC; (2) linear, mono- or difunctional crosslinking oligomers prepared by condensing an amine end cap with a diamine and a dianhydride; and (3) multidimensional, crosslinking oligomers having an aromatic hub and at least three radiating arms connected to the hub, each arm including a crosslinking end cap at its distal end and at least one imide linkage.
Blends, prepregs, and composites can be prepared from the oligomers.
Multidimensional oligomers can be prepared using ether-anhydride intermediates or etheramine intermediates formed by reacting a suitable hub with nitrophthalic anhydride or aminophenol.

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