Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...
Reexamination Certificate
2001-04-26
2003-06-03
Sanders, Kriellion A. (Department: 1714)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Processes of preparing a desired or intentional composition...
Reexamination Certificate
active
06573317
ABSTRACT:
The invention relates to a copolyether ester composition protected against the influence of light that contains a combination of a hindered amine photostabiliser (HALS) and a UV-light-absorbing organic compound. Such a copolyether ester composition is known and commercially available under the name of Hytrel UV20® from Du Pont De Nemours, USA; this composition contains 70 wt % of a copolyether ester based on butylene terephthalate and polytetramethylene oxide, 10 wt % of a hindered amine photostabiliser chosen from the group comprising 2,2,6,6-tetramethyl-substituted piperidyl esters of dicarboxylic acids (Tinuvin 144®, from Ciba-Geigy, Switzerland) and 10 wt % of a UV-light-absorbing compound, an optionally chlorinated 2-(2-hydroxy-3′,5′-di-tert-butyl-phenyl) benzotriazole. This composition also contains 10 wt % of a phenolic thermal-oxidative stabiliser, namely IRGANOX 1010®, from Ciba-Geigy, Switzerland. The composition is generally used as a masterbatch and must be mixed, in the desired concentration, with the copolyether ester compositions used in objects that are exposed to the effects of light. A very interesting application of such a composition is for example in ski boots. Besides high mechanical requirements, very high aesthetic requirements are imposed on this last application. Discolouration under the influence of light, for example, is absolutely undesirable.
The known composition according to the state of the art shows shortcomings especially as regards the retention of colour in ageing under the influence of light.
The aim of the invention is hence a copolyether ester composition that shows less discolouration.
The inventors have achieved this aim by using as the hindered amine photostabiliser a compound from the group of compounds having the general formula 1.
(1)
where
R
1
=C
n
H
2n
R
2
=H, C
m
H
2m+1
or
R
3
=H or an alkyl group with 1 to 12 carbon atoms
where
n=1, 2, 3, 4, 5 or 6
m=1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 or 12.
Preferably n is chosen to be at least 2. The best results are obtained when n=6 and
The copolyether ester composition according to the invention consequently contains the following components:
(1) a copolyether ester;
(2) a UV-light-absorbing compound;
(3) a hindered amine photostabiliser;
(4) optionally a thermal-oxidative stabiliser chosen from the group comprising phenolic compounds;
(5) optionally other additives;
characterised in that the hindered amine photostabiliser (component (3)) is chosen from the group of compounds having the general formula (1).
When the hindered amine photostabiliser of the invention is used in combination with a UV-light-absorbing compound it is moreover found that the presence of the phenolic thermal-oxidative stabiliser according to the state of the art is not necessary to ensure the retention of colour in ageing under the influence of light.
The composition according to invention can be obtained with the usual methods. For example by powder coating components (2) to (5) in the desired concentration onto the granules of the copolyether ester (component (1)) before these granules are processed, for example by means of injection-moulding, into the objects exposed to the influence of light. By using the so-called masterbatch technique, in which first granules with a high concentration of stabilisers are produced, which granules are then mixed, in the desired concentration, with copolyether ester granules that do not contain components (2) to (3), a composition with an accurate concentration of components (2) and (3) can be obtained.
The concentrations in which components (2) and (3) are present in the copolyether ester composition according to the invention may vary within a very wide range, and are partly determined by the conditions to which the objects obtained from the composition will be exposed. In general, these concentrations will vary between 0.05 and 1 wt %, relative to the copolyether ester. The ratio of the different stabilising components (2) and (3) in the composition may then vary within a wide range, depending on the desired properties and the copolyether ester used, for example between 0.1 and 10. If the composition is used as a mastermatch, the concentrations will of course be approximately at least a factor of 10 higher than in the composition for the final application. Preferably the concentrations will then lie between 0.5 and 20 wt %.
In principle, any copolyether ester containing hard segments composed of repeating units derived from at least one alkylene glycol and at least one aromatic or cycloaliphatic dicarboxylic acid and soft segments derived from at least one polyalkylene oxide glycol can be used as a copolyether ester for the composition according to the invention. Examples of alkylene glycols are ethylene glycol, propylene glycol and butylene glycol. Examples of aromatic dicarboxylic acids are terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid and 4,4-diphenyldicarboxylic acid. Examples of polyalkylene oxide glycols are polyethylene oxide glycol, polypropylene oxide glycol, polytetramethylene oxide glycol or combinations thereof, for example with ethylene-oxide-terminated polypropylene oxide glycol.
The preparation and properties of copolyether esters are known to a person skilled in the art and for example described in detail in
Thermoplastic Elastomers,
2nd Ed., Chapter 8, Carl Hanser Verlag (1996) ISBN 1-56990-205-4
, Handbook of Thermoplastics
, Ed. O. Otabisi, Chapter 17, Marcel Dekker Inc., New York 1997, ISBN 0-8247-9797-3, and the
Encyclopedia of Polymer Science and Engineering
, Vol. 12, pp. 75-117 (1988), John Wiley and Sons, and the references mentioned therein.
The composition according to the invention may also contain the usual additives, pigments and processing aids.
The invention will now be further elucidated with reference to the following examples and comparative experiments, without being limited hereto.
REFERENCES:
patent: 4426471 (1984-01-01), Berner
patent: 4524165 (1985-06-01), Musser et al.
patent: 5985961 (1999-11-01), Dailey et al.
patent: 196 07 187 (1996-08-01), None
patent: 0 885 924 (1998-12-01), None
patent: 52 024 255 (1977-02-01), None
Bonte Geert G. I. V.
Gijsman Pieter
DSM N.V.
Sanders Kriellion A.
LandOfFree
Light-stable copolyether ester composition does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Light-stable copolyether ester composition, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Light-stable copolyether ester composition will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-3163689