Chemistry of hydrocarbon compounds – Plural serial diverse syntheses – To produce aromatic
Patent
1989-05-04
1991-07-09
Pal, Asok
Chemistry of hydrocarbon compounds
Plural serial diverse syntheses
To produce aromatic
585415, 585660, C07C 1202, C07C 5333
Patent
active
050307827
ABSTRACT:
Aliphatics are aromatized in a two-stage catalytic upgrading process. In the first stage, aliphatic hydrocarbons are at least partially cracked and dehydrogenated to form an intermediate product stream. The extent and selectivity of the cracking and dehydrogenation reactions are preferably controlled to maintain heat balance in a second stage catalytic aromatization step.
In a preferred embodiment, a first aliphatic feedstream is cracked and dehydrogenated to form an intermediate product stream. The intermediate product stream is then mixed with a second aliphatic feedstream and contacted with a zeolite aromatization catalyst. Cracking and dehydrogenation of the first aliphatic feedstream is controlled to provide heat balanced aromatization of the combined streams.
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patent: 4784748 (1988-11-01), Avidan et al.
patent: 4912273 (1990-03-01), Harandi et al.
N. Y. Chen et al., "M2 Forming-A Process for Aromatization of Light Hydrocarbons", Ind. Eng. Chem. Process Des. Dev. 25, pp. 151-155 (1986).
Kirk-Othmer Encyclopedia of Chemical Technology, 3rd. ed., vol. 9, pp. 706-709 (1980).
Harandi Mohsen N.
Owen Hartley
Furr Jr. Robert B.
McKillop Alexander J.
Mobil Oil Corporation
Pal Asok
Speciale Charles J.
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