Ligands and catalyst systems thereof for ethylene...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C546S112000, C546S276400, C546S329000, C585S527000

Reexamination Certificate

active

11080170

ABSTRACT:
Mixed bis-imine pyridine ligands of formula (I), wherein Z1, which is different from Z2, is an optionally substituted aryl group; and Z2comprises an optionally substituted heterohydrocarbyl moiety, or an optionally substituted aryl group in combination with a metal, said optionally substituted aryl group being π-co-ordinated to the metal;mixed bis-imine pyridine complexes comprising a ligand of formula (I); mixed ionic bis-imine pyridine complexes comprising a ligand of formula (I); and processes for the production of alpha olefins from ethylene, using said complexes.

REFERENCES:
patent: 4728583 (1988-03-01), Yamazaki et al.
patent: 4822911 (1989-04-01), Fried
patent: 4912333 (1990-03-01), Roberts et al.
patent: 4944026 (1990-07-01), Arakawa et al.
patent: 5151604 (1992-09-01), Kohda et al.
patent: 5318935 (1994-06-01), Canich et al.
patent: 5726115 (1998-03-01), Horton et al.
patent: 5830629 (1998-11-01), Vizard et al.
patent: 5852145 (1998-12-01), McLain et al.
patent: 5888647 (1999-03-01), Yamane
patent: 5905014 (1999-05-01), Van de Bergh
patent: 5955555 (1999-09-01), Bennett
patent: 6002034 (1999-12-01), McLain et al.
patent: 6063881 (2000-05-01), Bennett
patent: 6103946 (2000-08-01), Brookhart et al.
patent: 6150482 (2000-11-01), Brookhart et al.
patent: 6214761 (2001-04-01), Bennett
patent: 6232259 (2001-05-01), Ittel et al.
patent: 6265500 (2001-07-01), Debras
patent: 6310153 (2001-10-01), Ittel et al.
patent: 6395668 (2002-05-01), van Baar et al.
patent: 6407188 (2002-06-01), Guan et al.
patent: 6414098 (2002-07-01), Engehausen et al.
patent: 6417305 (2002-07-01), Bennett
patent: 6417364 (2002-07-01), Lenges
patent: 6423848 (2002-07-01), Bennett
patent: 6432862 (2002-08-01), Bennett
patent: 6441117 (2002-08-01), Cameron
patent: 6451939 (2002-09-01), Britovsek et al.
patent: 6455660 (2002-09-01), Clutton et al.
patent: 6458739 (2002-10-01), Kimberley et al.
patent: 6458905 (2002-10-01), Schmidt et al.
patent: 6461994 (2002-10-01), Gibson et al.
patent: 6462152 (2002-10-01), Berardi et al.
patent: 6462155 (2002-10-01), Okuda
patent: 6465386 (2002-10-01), Maddox et al.
patent: 6472341 (2002-10-01), Kimberley et al.
patent: 6479601 (2002-11-01), Kerns et al.
patent: 6489497 (2002-12-01), Brookhart, III et al.
patent: 6521329 (2003-02-01), Aylward et al.
patent: 6534691 (2003-03-01), Culver et al.
patent: 6545108 (2003-04-01), Moody et al.
patent: 6548672 (2003-04-01), Gibson et al.
patent: 6555723 (2003-04-01), Schiffino
patent: 6559091 (2003-05-01), Moody et al.
patent: 6559252 (2003-05-01), Horton et al.
patent: 6583237 (2003-06-01), Imuta et al.
patent: 6605677 (2003-08-01), Lavoie et al.
patent: 6677267 (2004-01-01), Berardi et al.
patent: 6683141 (2004-01-01), Gibson et al.
patent: 6683187 (2004-01-01), De Boer et al.
patent: 6706891 (2004-03-01), Ponasik
patent: 6710006 (2004-03-01), De Boer et al.
patent: 6740715 (2004-05-01), Brookhart, III et al.
patent: 6825297 (2004-11-01), Devore et al.
patent: 6838540 (2005-01-01), Mitani et al.
patent: 7049442 (2006-05-01), De Boer et al.
patent: 7053020 (2006-05-01), De Boer et al.
patent: 7179871 (2007-02-01), De Boer et al.
patent: 2001/0000519 (2001-04-01), Bennett
patent: 2001/0016634 (2001-08-01), Ittel et al.
patent: 2002/0013431 (2002-01-01), Bennett
patent: 2002/0016425 (2002-02-01), De Boer et al.
patent: 2002/0016521 (2002-02-01), Culver et al.
patent: 2002/0019575 (2002-02-01), Schiffino
patent: 2002/0028941 (2002-03-01), De Boer et al.
patent: 2002/0035031 (2002-03-01), Berardi et al.
patent: 2002/0128409 (2002-09-01), De Boer et al.
patent: 2003/0036615 (2003-02-01), Brookhart, III et al.
patent: 2003/0045752 (2003-03-01), De Boer et al.
patent: 2003/0050494 (2003-03-01), Brookhart, III et al.
patent: 2003/0119921 (2003-06-01), De Boer et al.
patent: 2003/0125195 (2003-07-01), Britovsek et al.
patent: 2003/0144514 (2003-07-01), De Boer et al.
patent: 2003/0195110 (2003-10-01), Moody et al.
patent: 2003/0225228 (2003-12-01), Moody et al.
patent: 2004/0116758 (2004-06-01), De Boer et al.
patent: 2005/0014983 (2005-01-01), De Boer et al.
patent: 2005/0159601 (2005-07-01), De Boer et al.
patent: 0308728 (1989-03-01), None
patent: 1125928 (2001-08-01), None
patent: 1125987 (2001-08-01), None
patent: 0927201 (2004-04-01), None
patent: 04325504 (1992-11-01), None
patent: 418462 (1974-09-01), None
patent: 98/27124 (1998-06-01), None
patent: 99/02472 (1999-01-01), None
patent: WO 99/12981 (1999-03-01), None
patent: WO9951550 (1999-10-01), None
patent: 99/62967 (1999-12-01), None
patent: WO 00/50470 (2000-08-01), None
patent: WO 01/36379 (2001-05-01), None
patent: WO 02/28805 (2002-04-01), None
Lions et al, “Tridentate Chelate Compounds. I.” J. Am. Chem. Soc. (1957), vol. 79, 2733-38.
U.S. Appl. No. 10/739,715, filed Dec. 18, 2003, De Boer et al.
D. Vogt,Oligomerisation of ethylene to higher a-olefinsinApplied Homogeneous Catalysis with Organometallic CompoundsEd. B. Cornils, W.A. Herrmann vol. 1, Ch. 2.3.1.3, p. 245, VCH 1996.
D. van Leusen and B. Hessen, Organometallics, 2001, 20, pp. 224-226.
Chemical Abstracts, vol. 134, Columbus, Ohio, US; Abstract No. 231149, Radecka-Paryzek, W. et al., “Metal-ion-directed synthesis of homo- and heteronuclear dimetallic Schiff base podates,” Pol. J. Chem. 2001, 75(1), pp. 35-42.
Office Action dated Nov. 29, 2004 regarding U.S. Appl. No. 10/208,535, filed Jul. 30, 2002.
Amendment in response to the Office Action of Nov. 29, 2004 regarding U.S. Appl. No. 10/208,535, filed Jul. 30, 2002.
Lions, Francis et al. “Tridentals Chelate Compounds. I” J. Am. Chem. Soc. (1957), vol. 79, 2733-38.
Figgins, Paul et al. “Complexes of Iron (II), Co(II); and N(II) with Biacetyl-bis-methylimine, 2-pyridinal-methylimine and 2,6-pyridindial-bis-methylimine,” J.Am. Chem. Soc. (1960), vol. 82, 820-824.
Office Action of Mar. 23, 2005 in patent application TS1266 (U.S. Appl. No. 10/668,592, filed Sep. 23, 2003).
Response to Office Action of Mar. 23, 2005 in patent application TS1266 (U.S. Appl. No. 10/668,592, filed Sep. 23, 2003) dated Jun. 10, 2005.
George J. P. Britovsek et al., “Iron-Catalyzed Polyethylene Chain Growth on Zinc: Linear α-Olefins with a Poisson Distribution,” Angew. Chem. Int. Ed. 2002, 41, No. 3, pp. 489-491.
International Preliminary Examination Report for PCT/EP 03/10708 of Jan. 3, 2005.
U.S. Appl. No. 11/080,170, filed Mar. 15, 2005, De Boer et al.
“Iron-Based Catalysts With Exceptionally High Activities and Selectivities for Oligomerization of Ethylene to Linear α-Olefins,” B. L. Small and M. Brookhard disclosed inJ. Am. Chem. Soc.1998, 120, pp. 7143-7144.
“Oligomerisation of Ethylene by Bis(Imino)Pyridyliron and—Cobalt Complexes,” by G. J. P. Britovsek, S. Mastroianni, G. A. Solan, S. P. D. Baugh, C. Redshaw, V. C. Gibson, A. J. P. White, D. J. Williams, and M. R. J. Elsegood, as disclosed inChem. Eur. J. 2000, 6, pp. 2221-2231.
Olefin Polymerization with [{bis(imino)pyridyl}CO11Cl2]: Generation of the Active Species Involves CO1**, by T. Martijn Kooistra et al., Angewandte Chemie. International Edition, WILEY-VCH, Weinheim, DE, vol. 40, No. 24, Dec. 17, 2001, pp. 4719-4722.
“The Nature of the Active Species in Bis(imino)pyridyl Cobalt Ethylene Polymerisation Catalysts,” by Vernon C. Gibson, et al., Chemical Communications-Chemcom, Royal Society of Chemistry, GB, No. 21, 2001, pp. 2252-2253.
“Novel, Highly Active Iron and Cobalt Catalysts for Olefin Polymerization,” by Allison M. A. Bennett, Chemtech, Jul. 1999, pp. 24-28.
“Late Metal Catalysts for Ethylene Homo- and Copolymerization,” by Steven D. Ittel et al., Chemical Reviews, American Chemical Society, Easton, US, vol. 100, No. 4, 2000, pp. 1169-1203.
“Novel Olefin Polymerization Catalysts Based on Iron and Cobalt,” by George J. P. Britovsek et al., Chemical Communications-Chemcom, Roayl Society of Chemistry, GB, No. 7, 1998, pp. 849-850.
“Polymerization of Propylene by a New Generation of Iron Catalysts: Mechanisms of Chain Initiation, Propagati

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Ligands and catalyst systems thereof for ethylene... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Ligands and catalyst systems thereof for ethylene..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Ligands and catalyst systems thereof for ethylene... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3867922

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.