Ligand synthesis

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfonic acids or salts thereof

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C568S008000

Reexamination Certificate

active

11457996

ABSTRACT:
Ligand synthesis methods for the preparation of ligands having the formulawherein Q is selected from phosphorus, arsenic and antimony; wherein X1, X2and X3are carbon anions; and, wherein R15is selected from —SO3, —SO2N(R18), —CO2, —PO3, —AsO3, —SiO2, —C(CF3)2O; where R18is selected from a hydrogen, a halogen, a hydrocarbyl group and a substituted hydrocarbyl group, are disclosed. Also disclosed are methods of complexing the ligands with late transition metals to form catalyst complexes that catalyze polymerization reactions and/or Heck coupling reactions.

REFERENCES:
patent: 4689437 (1987-08-01), Murray
patent: 5760286 (1998-06-01), Brandvold
patent: 6060569 (2000-05-01), Bennett et al.
patent: 0 589 527 (1999-07-01), None
patent: WO 00/02890 (2000-01-01), None
patent: WO 0006615 (2000-02-01), None
Hearley, et al., New Single-Site Palladium Catalysis for the Nonalternative Copolymerization of Ethylene and Carbon Monoxide, ORGANOMETALLICS, vol. 24, pp. 2755-2763 (2005).
Drent, et al., Palladium catalysed copolymerization of ethene with alkylacrylates: polar commonomer built into the linear polymer chain, Chem. Commun. pp. 744-745 (2002).
Schultz, et al., Palladium(II) Complexes with Chelating P,O-Ligands as Catalysts for the Heck Reaction, SYNTHESIS No. 6, pp. 1005-1011 (2005).
Katho, et al., Formation and Solid State Structures of Highly Crystalline Guanidinium Salts of Sulfonated Tertiary Phosphanes, Adv. Synth. Catal. No. 3/4, pp. 278-282 (2002).
Genet, et al., Recent developments of palladium(O) catalyzed reactions in aqueous medium, J. Organometallic Chemistry, vol. 576, Issues 1 2, pp. 305-317 (1999).
Kaye, et al., The Use of Catalytic Amounts of CuCl and Other Improvements in the Benzyne Route to Biphenyl-Based Phosphine Ligands, Adv. Synth. Catal. No. 8, pp. 789-794 (2001.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Ligand synthesis does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Ligand synthesis, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Ligand synthesis will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3929068

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.