Leaching cobalt from metal-containing particles

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Iron group metal

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423 53, 423 54, 423138, 502 26, C22B 2300

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active

050664697

ABSTRACT:
A process is disclosed to extract cobalt and optionally, at least one metal value selected from the group consisting of molybdenum, nickel, tungsten, and vanadium from metal-containing particles, such as spent hydroprocessing catalysts particles containing carbon residue. In this process, the spent catalyst particles are roasted in an oxygen-containing gas at a temperature of from 400.degree. C. to 600.degree. C., and then the roasted catalyst particles are contacted with an aqueous solution of ammonia, ammonium salt, and hydrogen peroxide. The aqueous solution has an initial pH of at least 9.5 and an initial hydrogen peroxide concentration of from 0.02 to 0.2 M. That aqueous solution is maintained at a pH of greater than 9.5.

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