Liquid crystal cells – elements and systems – Particular structure – Having significant detail of cell structure only
Reexamination Certificate
1998-06-22
2001-02-06
Sikes, William L. (Department: 2811)
Liquid crystal cells, elements and systems
Particular structure
Having significant detail of cell structure only
C349S153000, C349S155000, C349S187000
Reexamination Certificate
active
06184954
ABSTRACT:
FIELD OF TECHNOLOGY
The present invention relates to a liquid crystal display apparatus, and to a liquid crystal display element used as an optical shutter.
RELATED TECHNOLOGY
Liquid crystal display elements have become practical for use in flat, large-screen display devices in information processing devices, particularly portable personal computers, and televisions and other video products. Of the various LCD elements available, the polymer dispersed type has been of particular interest in recent years.
This polymer dispersed LCD element comprises a pair of glass substrates with a conductive coating, and disposed therebetween a liquid crystal layer in which liquid crystals are dispersed in as droplets or networked crystals in a polymer matrix. Depending upon whether a voltage is applied to the liquid crystal layer, the LCD element switches between a state transmitting or dispersing incident light from a backlight.
A conventional liquid crystal display element is described next below with reference to 
FIG. 9A
, 
FIG. 9B
, 
FIG. 9C
, 
FIG. 12
, 
FIG. 21
, and FIG. 
22
. The structure of a polymer dispersed LCD element is shown first in 
FIG. 9A
 at normal temperature (e.g., 20° C.). LCD element 
200
 comprises glass plates 
51
 and 
52
, seal 
53
, liquid crystal 
541
 polymer matrix 
55
, and spacer 
56
.
The glass plates 
51
 and 
52
 each have a transparent electrode made from a conductive film of ITO (indium tin oxide). The polymer matrix 
55
 is a polymer compound with a three-dimensional networked structure. The liquid crystals 
54
 are liquid crystals dispersed in the polymer matrix 
55
. A liquid crystal layer 
57
 disposed between glass plates 
51
 and 
52
 is formed from the liquid crystals 
54
 and polymer matrix 
55
.
The seal 
53
 is coated to the circumferential edge of the glass plates 
51
 and 
52
, and seals the liquid crystal layer 
57
. A plurality of spacers 
56
 is distributed in the liquid crystal layer 
57
 to hold a constant gap width between the glass plates 
51
 and 
52
. A voltage application means, not shown in the figure, is disposed to the glass plates 
51
 and 
52
 for applying a desired voltage to the liquid crystal layer 
57
.
In a conventional polymer dispersed LCD element, the average particle diameter of spacers 
56
 is less than the gap width between the glass plates, and the internal pressure of the liquid crystal layer 
57
 is set lower than atmospheric pressure. Pressure pushing from the outside to the inside therefore acts on the liquid crystal layer 
57
, and the gap width between the two glass plates is held to the particle diameter of the spacer 
56
. It should be noted that the spacers 
56
 are the same as those used in a twisted nematic LCD element.
Referring below to 
FIGS. 9B and 9C
, phenomena occurring in the conventional polymer dispersed shown in 
FIG. 9A
 as a result of a rapid change in temperature are described. 
FIG. 9B
 illustrates the state when the LCD element 
200
, which is shown in 
FIG. 9A
 at a normal temperature, rises from normal temperature to a high temperature (85 degrees C in this example), and 
FIG. 9C
 illustrates the state when the LCD element 
200
 drops rapidly from the high temperature state shown in 
FIG. 9B
 to normal temperature.
As shown in 
FIG. 9A
, when the LCD element 
200
 is at normal temperature, substantially no pressure is applied by the glass plates 
51
 and 
52
 to the spacers 
56
 because the size of the spacers 
56
 is the same as the gap width. However, the volume of the matrix 
55
 and liquid crystals 
54
 increases when the temperature rises, and the internal pressure of the liquid crystal layer 
57
 therefore rises. Unlike the perimeter area, the middle portion of the glass plates 
51
 and 
52
 is not fixed by a seal 
53
 and therefore deforms due to the effect of this increased internal pressure, resulting in a gradual increase in the gap width from the perimeter area to the center. The expanded liquid crystals therefore collect in the center area, and the LCD element 
200
 deforms as shown in FIG. 
9
B.
When the LCD element 
200
 is then rapidly cooled to normal temperature from the state shown in 
FIG. 9B
, the liquid crystal layer 
57
 contracts. The liquid crystals concentrated in the center cannot completely return to the original condition at this time, however, and a large part thereof is left in the middle. The gap between the glass plates 
51
 and 
52
 is therefore different in this area as shown in FIG. 
9
C.
Irregularity in the thickness of the liquid crystal layer is thus induced in a conventional polymer dispersed LCD element as a result of expansion and contraction of the liquid crystal layer caused by a rapid change in temperature, and a dramatic deterioration in display quality occurs as a result.
A first object of the present invention is therefore to resolve the above-described conventional problem by providing a liquid crystal display element whereby distortion of the gap width resulting from a sudden change in temperature can be prevented, and uniformity of displayed images can be improved.
The configuration of a conventional LCD element is described next referring to the partially exploded perspective view in FIG. 
12
. LCD element 
140
 comprises glass plates 
131
a and 
131
b
, transparent electrodes 
132
a 
and 
132
b
, seal 
133
, conductive material 
134
a 
and 
134
b
, opening 
135
, active element formation area 
136
, and liquid crystal layer 
137
.
The glass plates 
131
a 
and 
131
b 
are transparent panels made of glass, each comprising an ITO (indium tin oxide) conductive film as a transparent electrode 
132
a 
and 
132
b
. A seal 
133
 is formed near the perimeter of the glass plates 
131
a 
or 
131
b
. The opening 
135
 is a discontinuity disposed in the seal 
133
, and is used for filling liquid crystals to the liquid crystal layer 
137
. Liquid crystals are injected to the liquid crystal layer 
137
 from the opening 
135
.
The active element formation area 
136
 is an area on transparent electrode 
132
b 
in which a TFT element is formed for each pixel of the LCD element 
140
. The conductive material 
134
a 
and 
134
b 
is a conductive paste coated to transparent electrode 
131
b
, and electrically connecting transparent electrode 
132
a 
and transparent electrode 
132
b. 
A vacuum injection method is generally used to inject a liquid crystal material to a conventional LCD element 
140
 thus comprised. In this method, an empty LCD element (
140
) with a liquid crystal layer 
137
 that has not been filled with liquid crystal, that is, an empty cell, is placed in a depressurized tank to create a vacuum inside the cell, and the tank is then returned to normal pressure with the opening 
135
 in contact with a liquid crystal material to inject the liquid crystal material to the cell.
In addition to penetrating the liquid crystal layer 
137
, the liquid crystal material also penetrates the gap between the glass plates 
131
 and 
132
 to the outside of the seal 
133
 (hereafter referred to as the “outside gap”) when a liquid crystal material is thus injected to an empty LCD element 
140
. This occurs as a result of capillary action due to the height of the seal 
133
, that is, the width between the glass plates 
131
 and 
132
, being a gap of only plural micrometers. It is therefore necessary to wash and remove any liquid crystal material that has penetrated this outside gap after the opening 
135
 is sealed.
However, when liquid crystals penetrating said outside gap are removed by washing in the above-described conventional LCD element, the conductive material 
134
a 
and 
134
b 
is contaminated or removed in certain cases. When this occurs, the impedance between the transparent electrodes 
132
a 
and 
132
b 
is significantly increased and conductivity is impaired, leading to deterioration of the image quality of displayed images.
Therefore, a second object of the present invention is to resolve the above-described conventional problem by providing a LCD element and manufacturing method whereby the conductive material 
134
a 
and 
134
b 
is protecte
Inoue Kazuo
Nishiyama Seiji
Uemura Tsuyoshi
Chowdhury Tarifur R.
Greenblum & Bernstein P.L.C.
Matsushita Electric - Industrial Co., Ltd.
Sikes William L.
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