Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1983-08-22
1985-05-21
Sneed, Helen M. S.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
528395, 528398, 528 9, 528223, 528224, 528271, 528287, 528362, 528374, 528373, C07F 900, C07F 938, C07F 970, C07F 909
Patent
active
045185344
ABSTRACT:
A layered oxide containing vanadium together with phosphorus or arsenic and an organic group may be prepared which has a unique layered structure of the formula: VORAO.sub.3.nS or VOROAO.sub.3.nS where A is phosphorus or arsenic, S is a solvent molecule, R is an unsubstituted or alkyl-, alkoxy- or aryl-substituted alkyl or aryl group, and n is zero or a positive number. These layered compounds are characterized in that the vanadium is substantially in a 4+ oxidation state and is present in an amount such that the molar ratio of A:V ranges from 0.8 to 1.2 throughout the oxide. Also the R groups are covalently bound to an A atom in the vanadium oxide layer directly through either carbon or oxygen atoms.
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Alberti et al., J. Inorg. Nucl. Chem., 40, 1113 (1978).
Jacobson Allan J.
Johnson Jack W.
Corcoran Edward M.
Exxon Research & Engineering Co.
Sneed Helen M. S.
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