Layered titanic acid, lamellar titanic acid, lamellar...

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

Reexamination Certificate

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C423S609000, C423S610000, C428S220000

Reexamination Certificate

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07455826

ABSTRACT:
A layered titanic acid produced by subjecting a layered titanate represented by a general formula: AxMy□zTi2−(y+z)O4, wherein A and M represent metals having a valence of 1 to 3 and being different from each other, □ represents a defect to be occupied by titanium, x is a positive and real number satisfying 0<x<1.0, y and z are positive and real numbers satisfying 0<y+z<1.0, to an acid treatment, to thereby substitute hydrogen ions or hydronium ions for 40 to 99% of A and/or M ions; a lamellar titanic acid produced by reacting the layered titanic acid with a basic compound, to thereby delaminate the layered titanic acid; and a lamellar titanium oxide produced by subjecting the lamellar titanic acid to a heat treatment or the like.

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Sasaki, Takayoshi et al , “A Mixed Alkali Titanate with the Lepidocrocite-like Layered Structure. Preparation, Crystal Structure, Protonic Form, and Acid-Base Intercalation Properties”, Chem. Mater., 1998, vol. 10, pp. 4123-4128.
Sasaki, Takayoshi et al., “Osmotic Swelling to Exfoliation. Exceptionally High Degrees of a Layered Titanate”, J. Am. Chem. Soc., 1998, vol. 120, pp. 4862-4869.
Groult, D. et al., “Nouveaux oxydes à structure en feuillets: Les titanates de potassium non-stoechiométriques Kx(MyTi2-y)O4”,Journal of Solid State Chemistry, vol. 32, 1980, pp. 289-296.
Sasaki, Takayoshi et al., “A Mixed Alkali Metal Titanate with the Lepidocrocite-like Layered Structure. Preparation, Crystal Structure, Protonic Form, and Acid-Base Intercalation Properties”,Chem. Mater., 1998, vol. 10, pp. 4123-4128.
Sasaki, Takayoshi et al., “Osmotic Swelling to Exfoliation. Exceptionally High Degrees of a Layered Titanate”,J. Am. Chem. Soc., 1998, vol. 120, pp. 4862-4869.

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