Late transition metal catalysts for olefin oligomerizations

Details Late transition metal catalysts for olefin oligomerizations Late transition metal catalysts for olefin oligomerizations

2011-08-09

2011-08-09

McDonough, James E (Department: 1731)

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Organic compound containing

C502S100000, C502S162000, C502S167000, C502S200000, C502S439000

Reexamination Certificate

active

07994086

ABSTRACT:
A series of novel late transition metal catalysts for olefin oligomerization have been invented. The catalysts demonstrate high activity and selectivity for linear α-olefins.

REFERENCES:
patent: 3991259 (1976-11-01), Piekarski et al.
patent: 4377528 (1983-03-01), Beach et al.
patent: 4824977 (1989-04-01), Devon et al.
patent: 4904808 (1990-02-01), Devon et al.
patent: 5658982 (1997-08-01), Baardman et al.
patent: 5777087 (1998-07-01), Kohlpaintner et al.
patent: 5994255 (1999-11-01), Nickias et al.
patent: 6184381 (2001-02-01), Ikariya et al.
patent: 6225487 (2001-05-01), Guram
patent: 6307087 (2001-10-01), Buchwald et al.
patent: 6323353 (2001-11-01), Sumi et al.
patent: 6525210 (2003-02-01), Zhang et al.
patent: 6632901 (2003-10-01), McCullough
patent: 6710007 (2004-03-01), Brookhart et al.
patent: 7199075 (2007-04-01), Speiser et al.
patent: 7247687 (2007-07-01), Cherkasov et al.
patent: 2001/0044508 (2001-11-01), Loveday et al.
patent: 2005/0003955 (2005-01-01), Zhao et al.
patent: 0 479 541 (1992-04-01), None
patent: 09-255713 (1997-09-01), None
patent: WO 00/02887 (2000-01-01), None
patent: WO 01/38337 (2001-05-01), None
patent: WO 2004/037837 (2004-05-01), None
patent: WO 2004/037869 (2004-05-01), None
Christmann et al.,Experimental and Theoretical Investigations of New Dinuclear Palladium Complexes as Precatalysts for the Amination of Aryl Chlorides, J. Am. Chem. Soc., 2006, vol. 128, No. 19, pp. 6376-6390.
Daniel,Quantitative Chemical Analysis, 5th Edition, 1982, pp. 306-329.
Elvers et al.,Ed. Ullmann's Encyclopedia of Industrial Chemistry, VCH Verlagsgesellschaft mbH, Weinheim, 1989, vol. A13, pp. 243-247 and 275-276.
Fabian et al.,Modeling the Chromatographic Enantioseparation of Aryl- and Hetarylcarbinols on ULMO, a Brush-type Chiral Stationary Phase, by 3D-QSAR Technique, Chirality, vol. 15, No. 3, pp. 271-275.
Fox et al.,Highly Active and Selective Catalysts for the Formation of α-Aryl Ketones, J. Am. Chem. Soc., 2000, vol. 122, No. 7, pp. 1360-1370.
Gandelman et al.,The First Observation and Kinetic Evaluation of a Single Step Metal Insertion into a C-C Bond, Journal of the American Chemical Society, 2000, vol. 122, No. 40, pp. 9848-9849.
Kamigaito et al.,Transition Metal-Catalyzed Living Radical Polymerization: Latest Advances, American Chemical Society, Division of Polymer Chemistry, 2002, vol. 43, No. 2, pp. 3-4 (Abstract).
Kaminsky et al.,Fluorinated Half-Sandwich Complexes as Catalysts in Syndiospecific Styrene Polymerization, Macromolecules, 1997, vol. 30, No. 25, pp. 7647-7650.
Kocovsky et al.,Palladium(II)Complexes of 2-Dimethylamino-2′-diphenylphosphino-1,1′-binaphthyl(MAP)with Unique P,Co-Coordination and Their Catalytic Activity in Allylic Substitution, Hartwig-Buchwalk Amination, and Suzuki Coupling, J. Am. Chem. Soc., 1999, vol. 121, No. 33, pp. 7714-7715.
McDonough,Thermodynamics and Kinetic Studies of Ligand Binding, Oxidative Addition, and Group/Atom Transfer in Group VI Metal Complexes, University of Miami, 2005, pp. 66.
Milani et al.,Highly Efficient Catalytic System for the CO/Styrene Copolymerization: Toward the Stabilization of the Active Species, Organometallics, 2000, vol. 19, No. 17, pp. 3435-3441.
Nozaki,Tacticity in Ethylene/Carbon Monoxide/Vinyl Co- and Terpolymerizations, Stereoselective Polymerization with Single-Site Catalysts, CRC Press, 2008, pp. 577-591.
Old et al.,A Highly Active Catalyst for Palladium-Catalyzed Cross-Coupling Reactions: Room-Temperature Suzuki Couplings and Amination of Unactivated Aryl Chlorides, J. Am. Chem. Soc., 1998, vol. 120, pp. 9722-9723.
Pedeutour et al.,Influence of X Ligand Nature in the Activation Process of racEt(Ind)2ZrX2by Methylaluminoxane, J. Mol. Catalysis A: Chemical, 2001, vol. 176, pp. 87-94.
Qian et al.,Synthesis and Polymerization Behavior of Various Substituted Half-Sandwich Titanium Complexes Cp'TiCl2(OR)as Catalyst for Syndiotactic Polystyrene, J. Mol. Cat., 2004, vol. 208, pp. 45-54.
Shiver et al.,Inorganic Chemistry, 3rd Edition, 1999, pp. 245-247, 467-482 and 562.
Vogt,Oligomerization of Ethylene to Higher Linear α-Olefins, Ed. Applied Homogeneous Catalysis with Organometallic Compounds, A Comprehensive Handbook, VCH Verlagsgesellschaft mbH, 1996, vol. 1, pp. 245-258.
Wolfe et al.,Highly Active Palladium Catalysts for Suzuki Coupling Reactions, J. Am. Chem. Soc., 1999, vol. 121, pp. 9550-9561.
Derwent Adbstract, CAS Registry No. 213697-53-1, [1,1′-Biphenyl]-2-amine, 2′-(dicyclohexylphosphino)-N,N-dimethyl-(9C1).
http://en.wikipedia.org/wiki/Ligand—field—theory.
http://en.wikipedia.org/wiki/Ligand.

Affiliated with

Also associated with

Rating

Late transition metal catalysts for olefin oligomerizations does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Late transition metal catalysts for olefin oligomerizations, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Late transition metal catalysts for olefin oligomerizations will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2633100