Laser zone melted Bi--Sr--Ca--Cu--O thick films

Superconductor technology: apparatus – material – process – High temperature – per se – Having tc greater than or equal to 150 k

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156610, 427 531, 427 62, 437910, 428930, 505729, H01L 3924, H01L 3900

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050156187

ABSTRACT:
A method for preparing a highly aligned thick film of superconducting bismuth strontium calcium copper oxide ceramic material to improve its critical current density. A film about 5-200 .mu.m thick of bismuth strontium calcium copper oxide is deposited on a suitable substrate. The ratios of Bi:(Sr, Ca):Cu in the film are about 2:3:2 to 2:4:3. A laser beam is translated over the deposited film at a rate of about 0.2-15 cm/hr while the film is held at a temperature of about 500.degree.-950.degree. C. The beam is about 0.01-0.50 cm wide along the direction of translation, and provides about 0.2-10W of optical power to the film. The temperature and the beam translation rate, width, and optical power are selected to permit zone melting and resolidification of the film to form the highly aligned thick film of superconducting bismuth strontium calcium copper oxide ceramic material. The J.sub.c may, if desired, be further improved by annealing the resolidified film at about 900.degree.-965.degree. C. for about 1-300 hr.

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