Lanthanum tantalate photocatalysts

Chemistry of inorganic compounds – Rare earth compound

Reexamination Certificate

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C502S303000, C423S579000, C423S658200

Reexamination Certificate

active

07553464

ABSTRACT:
A substantially pure phase LaTaO4photocatalyst is prepared by grinding precursors with mixture of at least two different sizes of high-density yttrium-stabilized zirconia balls to a very fine particle size and calcining the ground precursors. The LaTaO4photocatalyst prepared by this method is useful in photolysis of water.

REFERENCES:
patent: 6685909 (2004-02-01), Elder et al.
patent: 6878666 (2005-04-01), Domen et al.
patent: 2002/0151434 (2002-10-01), Domen et al.
patent: 2002/0155948 (2002-10-01), Inoue
International Search Report mailed Jun. 27, 2006 for PCT/US05/27284 filed Aug. 1, 2005 corresponding to this application.
Hwang, D. W. et al, “Photocatalytic Water Splitting Over Highly Donor-Doped (110) Layered Perovskites,” Journal of Catalysis 193, 40-48 (2000).
Kudo, A. et al., “Water Splitting into H2 and O2 on New Sr2M2O7 (M=Nb and Ta) Photocatalysts with Layered Perovskite Structures: Factors Affecting the Photocatalytic Activity,” J. Phys. Chem. B 2000, 104, 571-575.
Machida, M. et al., “Photocatalytic Property and Electronic Structure of Lanthanide Tantalates, LnTaO4n (Ln=La, Ce, Pr, Nd, and Sm),” J. Phys. Chem. B 2001, 105, 3289-3294.

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